A1 Journal article (refereed)
Cocrystal trimorphism as a consequence of the orthogonality of halogen- and hydrogen-bonds synthons (2019)
Topić, F., Lisac, K., Arhangelskis, M., Rissanen, K., Cinčić, D., & Friščić, T. (2019). Cocrystal trimorphism as a consequence of the orthogonality of halogen- and hydrogen-bonds synthons. Chemical Communications, 55(93), 14066-14069. https://doi.org/10.1039/C9CC06735C
JYU authors or editors
Publication details
All authors or editors: Topić, Filip; Lisac, Katarina; Arhangelskis, Mihails; Rissanen, Kari; Cinčić, Dominik; Friščić, Tomislav
Journal or series: Chemical Communications
ISSN: 1359-7345
eISSN: 1364-548X
Publication year: 2019
Volume: 55
Issue number: 93
Pages range: 14066-14069
Publisher: Royal Society of Chemistry
Publication country: United Kingdom
Publication language: English
DOI: https://doi.org/10.1039/C9CC06735C
Publication open access: Not open
Publication channel open access:
Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/67393
Abstract
True trimorphic cocrystals, i.e. multi-component molecular crystals of identical composition that exhibit three polymorphic structures, are exceedingly rare and so far no halogen-bonded cocrystal system has been reported to exhibit trimorphism. Here we describe a unique example of a trimorphic cocrystal exhibiting both hydrogen and halogen bonds in which the differences between polymorphs reveal their orthogonality, evident by the apparently independent variation of well-defined hydrogen- and halogen-bonded motifs.
Keywords: supramolecular chemistry; crystals; chemical bonds; hydrogen bonds
Contributing organizations
Ministry reporting: Yes
Reporting Year: 2019
JUFO rating: 2