Haloniumsupramolecular Chemistry: New Molecular Machines and Nanoreactors (HaloChem)
Main funder
Funder's project number: 317259
Funds granted by main funder (€)
- 582 340,00
Funding program
Project timetable
Project start date: 01/09/2018
Project end date: 31/08/2022
Summary
TThe project will prepare new molecular machines and nanocapsules which are based on [N-I+-N] halogen bond. The prepared molecular machines (catenanes and rotaxanes) and nanocapsules have, as their construction units, highly reactive iodonium ions.
These iodonium ions are efficient reagents in organic synthesis, thus combining the machine-like behaviour or the confined space inside the capsules, new chemical reactions are possible or the old reactions can be controlled in a new way. The structures and reactivities of the new molecular machines and nanocapsules will be studied using the most modern structural and synthetic chemistry techniques. The proposed research will pave way to a completely new research area with Supramolecular chemistry, namely Haloniumsupramolecular Chemistry.
These iodonium ions are efficient reagents in organic synthesis, thus combining the machine-like behaviour or the confined space inside the capsules, new chemical reactions are possible or the old reactions can be controlled in a new way. The structures and reactivities of the new molecular machines and nanocapsules will be studied using the most modern structural and synthetic chemistry techniques. The proposed research will pave way to a completely new research area with Supramolecular chemistry, namely Haloniumsupramolecular Chemistry.
Principal Investigator
Primary responsible unit
Follow-up groups
Related publications and other outputs
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- The “nitrogen effect” : Complexation with macrocycles potentiates fused heterocycles to form halogen bonds in competitive solvents (2023) Twum, Kwaku; et al.; A1; OA
- Toward Near-Infrared Emission in Pt(II)-Cyclometallated Compounds : From Excimers’ Formation to Aggregation-Induced Emission (2023) Lázaro, Ariadna; et al.; A1; OA
- Carbonyl hypoiodites from pivalic and trimesic acid and their silver(I) intermediates (2022) Ward, Jas S.; et al.; A1; OA
- Dimeric iodine(i) and silver(i) cages from tripodal N-donor ligands via the [N–Ag–N]+ to [N–I–N]+ cation exchange reaction (2022) Taipale, Essi; et al.; A1; OA
- Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines (2022) Ward, Jas S.; et al.; A1; OA
- Selective gas adsorption by calixarene-based porous octahedral M32 coordination cages (2022) Khariushin, Ivan, V.; et al.; A1; OA
- Synthetic and structural studies on the effect of non-covalent interactions on N(sp²)-heterocyclic molecules (2022) Taipale, Essi; G5; OA; 978-951-39-9039-8
- A “nucleophilic” iodine in a halogen-bonded iodonium complex manifests an unprecedented I+···Ag+ interaction (2021) Yu, Shilin; et al.; A1
- Carbonyl Hypoiodites as Extremely Strong Halogen Bond Donors (2021) Yu, Shilin; et al.; A1; OA
- Dihypoiodites stabilised by 4-ethylpyridine through O–I–N halogen bonds (2021) Kramer, Eric; et al.; A1; OA
