A1 Journal article (refereed)
Macrocyclic complexes based on [N⋯I⋯N]+ halogen bonds (2021)

Yu, S., Kalenius, E., Frontera, A., & Rissanen, K. (2021). Macrocyclic complexes based on [N⋯I⋯N]+ halogen bonds. Chemical Communications, 57(93), 12464-12467. https://doi.org/10.1039/D1CC05616F

JYU authors or editors

Publication details

All authors or editors: Yu, Shilin; Kalenius, Elina; Frontera, Antonio; Rissanen, Kari

Journal or series: Chemical Communications

ISSN: 1359-7345

eISSN: 1364-548X

Publication year: 2021

Volume: 57

Issue number: 93

Pages range: 12464-12467

Publisher: Royal Society of Chemistry (RSC)

Publication country: United Kingdom

Publication language: English

DOI: https://doi.org/10.1039/D1CC05616F

Publication open access: Openly available

Publication channel open access: Partially open access channel

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/78869

Abstract

New 1–2 nm macrocyclic iodine(I) complexes prepared VIA a simple ligand exchange reaction manifest rigid 0.5–1 nm cavities that bind the hexafluorophosphate anion in the gas phase. The size of the cavities and the electrostatic interactions with the iodine(I) cations influence the anion binding properties of these macrocyclic complexes.

Keywords: coordination complexes; halogens; iodine; chemical bonds

Contributing organizations

Related projects

Ministry reporting: Yes

Reporting Year: 2021

JUFO rating: 2