A1 Journal article (refereed)
Do 2-coordinate iodine(I) and silver(I) complexes form Nucleophilic Iodonium Interactions (NIIs) in solution? (2022)


Wilcox, S., Sethio, D., Ward, J. S., Frontera, A., Lindh, R., Rissanen, K., & Erdelyi, M. (2022). Do 2-coordinate iodine(I) and silver(I) complexes form Nucleophilic Iodonium Interactions (NIIs) in solution?. Chemical Communications, 58(32), 4977-4980. https://doi.org/10.1039/D2CC00994C


JYU authors or editors


Publication details

All authors or editors: Wilcox, Scott; Sethio, Daniel; Ward, Jas S; Frontera, Antonio; Lindh, Roland; Rissanen, Kari; Erdelyi, Mate

Journal or series: Chemical Communications

ISSN: 1359-7345

eISSN: 1364-548X

Publication year: 2022

Publication date: 01/04/2022

Volume: 58

Issue number: 32

Pages range: 4977-4980

Publisher: Royal Society of Chemistry (RSC)

Publication country: United Kingdom

Publication language: English

DOI: https://doi.org/10.1039/D2CC00994C

Publication open access: Openly available

Publication channel open access: Partially open access channel

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/80629


Abstract

The interaction of a [bis(pyridine)iodine(I)]+ cation with a [bis(pyridine)silver(I)]+ cation, in which an iodonium ion acts as nucleophile by transferring electron density to the silver(I) cation, is reinvestigated herein. No measurable interaction is observed between the cationic species in solution by NMR; DFT reveals that if there is an attractive interaction between this complexes in solution, it is dominantly the π-π interaction of pyridines


Keywords: silver; iodine; chemical compounds; crystallography


Contributing organizations


Ministry reporting: Yes

Reporting Year: 2022

Preliminary JUFO rating: 2


Last updated on 2022-20-09 at 15:40