A1 Journal article (refereed)
Do 2-coordinate iodine(I) and silver(I) complexes form Nucleophilic Iodonium Interactions (NIIs) in solution? (2022)


Wilcox, S., Sethio, D., Ward, J. S., Frontera, A., Lindh, R., Rissanen, K., & Erdelyi, M. (2022). Do 2-coordinate iodine(I) and silver(I) complexes form Nucleophilic Iodonium Interactions (NIIs) in solution?. Chemical Communications, 58(32), 4977-4980. https://doi.org/10.1039/D2CC00994C


JYU authors or editors


Publication details

All authors or editorsWilcox, Scott; Sethio, Daniel; Ward, Jas S; Frontera, Antonio; Lindh, Roland; Rissanen, Kari; Erdelyi, Mate

Journal or seriesChemical Communications

ISSN1359-7345

eISSN1364-548X

Publication year2022

Publication date01/04/2022

Volume58

Issue number32

Pages range4977-4980

PublisherRoyal Society of Chemistry (RSC)

Publication countryUnited Kingdom

Publication languageEnglish

DOIhttps://doi.org/10.1039/D2CC00994C

Publication open accessOpenly available

Publication channel open accessPartially open access channel

Publication is parallel published (JYX)https://jyx.jyu.fi/handle/123456789/80629


Abstract

The interaction of a [bis(pyridine)iodine(I)]+ cation with a [bis(pyridine)silver(I)]+ cation, in which an iodonium ion acts as nucleophile by transferring electron density to the silver(I) cation, is reinvestigated herein. No measurable interaction is observed between the cationic species in solution by NMR; DFT reveals that if there is an attractive interaction between this complexes in solution, it is dominantly the π-π interaction of pyridines


Keywordssilveriodinechemical compoundscrystallography


Contributing organizations


Ministry reportingYes

Reporting Year2022

JUFO rating2


Last updated on 2024-30-04 at 18:25