A1 Journal article (refereed)
Ligand exchange among iodine(I) complexes (2022)


Yu, S., & Ward, J. S. (2022). Ligand exchange among iodine(I) complexes. Dalton Transactions, 51(12), 4668-4674. https://doi.org/10.1039/D1DT04309A


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Publication details

All authors or editorsYu, Shilin; Ward, Jas S.

Journal or seriesDalton Transactions

ISSN1477-9226

eISSN1477-9234

Publication year2022

Publication date17/02/2022

Volume51

Issue number12

Pages range4668-4674

PublisherRoyal Society of Chemistry (RSC)

Publication countryUnited Kingdom

Publication languageEnglish

DOIhttps://doi.org/10.1039/D1DT04309A

Publication open accessOpenly available

Publication channel open accessPartially open access channel

Publication is parallel published (JYX)https://jyx.jyu.fi/handle/123456789/80506


Abstract

A detailed investigation of ligand exchange between iodine(I) ions in [N⋯I⋯N]+ halogen-bonded complexes is presented. Ligand exchange reactions were conducted to successfully confirm whether iodine(I) complex formation, via the classical [N⋯Ag⋯N]+ to [N⋯I⋯N]+ cation exchange reaction from their analogous Ag+ complexes, could be determined solely by using 1H NMR spectroscopy. In instances where the formation of the iodine(I) complex was unclear or in low yield by the traditional cation exchange reaction, a ligand exchange reaction was used to form the desired iodine(I) complexes in a quantitative manner. Mixing two homoleptic [N⋯I⋯N]+ iodine(I) complexes in 1 : 1 ratio was found to undergo a statistical ligand exchange, with 1H NMR studies showing that the preferred formation of the relative heteroleptic [N1⋯I⋯N2]+ complexes increases with greater differences in the Lewis basicities of two XB acceptors of the complexes involved.


Keywordscoordination complexeshalogensiodineligandschemical bonds


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Ministry reportingYes

Reporting Year2022

JUFO rating1


Last updated on 2024-03-04 at 18:27