A1 Journal article (refereed)
Self-Assembly and Characterisation of Grid-Type Iron(II), Cobalt(II) and Zinc(II) Complexes (2003)

Patroniak, V., Baxter, Paul N. W., Lehn, J.-M., Kubicki, M., Nissinen, M., & Rissanen, K. (2003). Self-Assembly and Characterisation of Grid-Type Iron(II), Cobalt(II) and Zinc(II) Complexes. European Journal of Inorganic Chemistry, 2003(22), 4001-4009. https://doi.org/10.1002/ejic.200300330

JYU authors or editors

Publication details

All authors or editors: Patroniak, Violetta; Baxter, Paul N. W.; Lehn, Jean-Marie; Kubicki, Maciej; Nissinen, Maija; Rissanen, Kari

Journal or series: European Journal of Inorganic Chemistry

ISSN: 1434-1948

eISSN: 1099-0682

Publication year: 2003

Volume: 2003

Issue number: 22

Pages range: 4001-4009

Publisher: Wiley

Publication country: United Kingdom

Publication language: English

DOI: https://doi.org/10.1002/ejic.200300330

Publication open access: Not open

Publication channel open access: 

Abstract

The reaction of the ligands 5 and 6, containing two tridentate binding units, with iron(II), cobalt(II) and zinc(II) leads to the self-assembly of supramolecular architectures of [2 × 2] grid type containing four ions in octahedral coordination sites. The grid-type structures have been assigned on the basis of the spectroscopic data in solution, and confirmed in the solid state in the case of complexes 6b and 6c by X-ray crystallography. The latter study revealed that each metal ion is situated in a distorted octahedral coordination environment comprising two N,N,O ligand donor sets.

Keywords: supramolecular chemistry

Free keywords: self-assembly

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Ministry reporting: Yes

Preliminary JUFO rating: Not rated