A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
Phase-selective low molecular weight organogelators derived from allylated D-mannose (2022)
Mattsson, I., Lahtinen, M., Sitdikov, R., Wank, B., Saloranta-Simell, T., & Leino, R. (2022). Phase-selective low molecular weight organogelators derived from allylated D-mannose. Carbohydrate research, 518, Article 108596. https://doi.org/10.1016/j.carres.2022.108596
JYU-tekijät tai -toimittajat
Julkaisun tiedot
Julkaisun kaikki tekijät tai toimittajat: Mattsson, Ida; Lahtinen, Manu; Sitdikov, Ruzal; Wank, Bianca; Saloranta-Simell, Tiina; Leino, Reko
Lehti tai sarja: Carbohydrate research
ISSN: 0008-6215
eISSN: 1873-426X
Julkaisuvuosi: 2022
Ilmestymispäivä: 01.06.2022
Volyymi: 518
Artikkelinumero: 108596
Kustantaja: Elsevier BV
Julkaisumaa: Alankomaat
Julkaisun kieli: englanti
DOI: https://doi.org/10.1016/j.carres.2022.108596
Linkki tutkimusaineistoon: https://dx.doi.org/10.5517/ccdc.csd.cc2b4qfn
Julkaisun avoin saatavuus: Avoimesti saatavilla
Julkaisukanavan avoin saatavuus: Osittain avoin julkaisukanava
Julkaisu on rinnakkaistallennettu (JYX): https://jyx.jyu.fi/handle/123456789/81974
Lisätietoja: Complete crystallographic data for the structural analysis have been deposited with the Cambridge Crystallographic Data Centre, CCDC no. 2149491 (compound 3) and 2149492 (compound 4),
https://dx.doi.org/10.5517/ccdc.csd.cc2b4qfn and https://dx.doi.org/10.5517/ccdc.csd.cc2b4qgp.
Tiivistelmä
In the last decades, synthesis and design of low molecular weight organogelators has gained increasing attention due to their versatile use in, for example, cosmetics, biomedicine and oil spill remediation. In this work, three potential gelators have been prepared from allylated d-mannose. Both the gelators and the corresponding gels formed were thoroughly characterized by crystallography, FTIR spectroscopy, SEM, rheometry and NMR spectroscopy, in solution and in solid state. The results showed that two of the compounds phase-selectively form gels with hydrocarbon solvents. The most promising gelator compound is alkene terminated, with the unsaturated end functionality not critical for gel formation, tentatively providing the possibility for customizing the gelation properties by further chemical modification. Alternatively, the alkene group could possibly be utilized as a linker for future coupling to carrier materials or surfaces to further increase the mechanical strength of the gel.
YSO-asiasanat: geelit; monosakkaridit; hiilihydraatit; kidetiede; NMR-spektroskopia; infrapunaspektroskopia; hyötykäyttö
Vapaat asiasanat: D-mannoosi
Liittyvät organisaatiot
OKM-raportointi: Kyllä
Raportointivuosi: 2022
JUFO-taso: 1
