A1 Journal article (refereed)
Allylcytisine as a convenient scaffold for the construction of the π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] with the unusual anionic 1D-coordination polymer (2022)

Slyvka, Y., Goreshnik, E., Pokhodylo, N., Morozov, D., Tupychak, M., & Mys'kiv, M. (2022). Allylcytisine as a convenient scaffold for the construction of the π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] with the unusual anionic 1D-coordination polymer. Polyhedron, 224, Article 116022. https://doi.org/10.1016/j.poly.2022.116022

JYU authors or editors

Publication details

All authors or editors: Slyvka, Yurii; Goreshnik, Evgeny; Pokhodylo, Nazariy; Morozov, Dmitry; Tupychak, Mykola; Mys'kiv, Marian

Journal or series: Polyhedron

ISSN: 0277-5387

eISSN: 1873-3719

Publication year: 2022

Volume: 224

Article number: 116022

Publisher: Elsevier BV

Publication country: United Kingdom

Publication language: English

DOI: https://doi.org/10.1016/j.poly.2022.116022

Publication open access: Not open

Publication channel open access:

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/86095

Abstract

The aim of this work is to develop a novel π-coordination compound with unusual architecture using allylcytisine (Acyt) as a suitable scaffold. The synthesis and structural characterization of {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] (1) and Acyt itself have been performed, accompanied by quantum chemical studies. A distinctive feature of structure 1 is the formation of H-bonded pairs of two {Acyt(H+)} cations, showing the non-equivalent participation of its allyl group regarding to Cu+ coordination, thus forcing the organization of the acentric structure 1 with the unusually organized anionic copper(I) halide 1D-coordination polymer.

Free keywords: Copper(I); η2-Interaction; cytisine; allyl derivative; crystal structure

Contributing organizations

Ministry reporting: Yes

Reporting Year: 2022

JUFO rating: 1