A1 Journal article (refereed)
Carbonyl hypoiodites from pivalic and trimesic acid and their silver(I) intermediates (2022)


Ward, J. S., Martõnova, J., Wilson, L. M. E., Kramer, E., Aav, R., & Rissanen, K. (2022). Carbonyl hypoiodites from pivalic and trimesic acid and their silver(I) intermediates. Dalton Transactions, 51(38), 14646-14653. https://doi.org/10.1039/d2dt01988d


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Publication details

All authors or editorsWard, Jas S.; Martõnova, Jevgenija; Wilson, Laura M. E.; Kramer, Eric; Aav, Riina; Rissanen, Kari

Journal or seriesDalton Transactions

ISSN1477-9226

eISSN1477-9234

Publication year2022

Publication date05/09/2022

Volume51

Issue number38

Pages range14646-14653

PublisherRoyal Society of Chemistry (RSC)

Publication countryUnited Kingdom

Publication languageEnglish

DOIhttps://doi.org/10.1039/d2dt01988d

Publication open accessOpenly available

Publication channel open accessPartially open access channel

Publication is parallel published (JYX)https://jyx.jyu.fi/handle/123456789/83247


Abstract

The first tris(O–I–N) carbonyl hypoiodites have been synthesised based on trimesic acid and pyridine or 4-methylpyridine, with their structures definitively confirmed by single crystal X-ray diffraction (SCXRD). The more soluble carbonyl hypoiodites based on pivalic acid have also been studied via NMR, SCXRD, and computational analyses, enabling the study of the direct silver(I) precursor and intermediates of the resulting carbonyl hypoiodites generated using a range of substituted pyridines.


Keywordscoordination complexeshalogensiodinesilvercarbonylschemical bonds


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Ministry reportingYes

Reporting Year2022

JUFO rating1


Last updated on 2024-10-03 at 17:07