A1 Journal article (refereed)
Carbonyl hypoiodites from pivalic and trimesic acid and their silver(I) intermediates (2022)
Ward, J. S., Martõnova, J., Wilson, L. M. E., Kramer, E., Aav, R., & Rissanen, K. (2022). Carbonyl hypoiodites from pivalic and trimesic acid and their silver(I) intermediates. Dalton Transactions, 51(38), 14646-14653. https://doi.org/10.1039/d2dt01988d
JYU authors or editors
Publication details
All authors or editors: Ward, Jas S.; Martõnova, Jevgenija; Wilson, Laura M. E.; Kramer, Eric; Aav, Riina; Rissanen, Kari
Journal or series: Dalton Transactions
ISSN: 1477-9226
eISSN: 1477-9234
Publication year: 2022
Publication date: 05/09/2022
Volume: 51
Issue number: 38
Pages range: 14646-14653
Publisher: Royal Society of Chemistry (RSC)
Publication country: United Kingdom
Publication language: English
DOI: https://doi.org/10.1039/d2dt01988d
Publication open access: Openly available
Publication channel open access: Partially open access channel
Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/83247
Abstract
The first tris(O–I–N) carbonyl hypoiodites have been synthesised based on trimesic acid and pyridine or 4-methylpyridine, with their structures definitively confirmed by single crystal X-ray diffraction (SCXRD). The more soluble carbonyl hypoiodites based on pivalic acid have also been studied via NMR, SCXRD, and computational analyses, enabling the study of the direct silver(I) precursor and intermediates of the resulting carbonyl hypoiodites generated using a range of substituted pyridines.
Keywords: coordination complexes; halogens; iodine; silver; carbonyls; chemical bonds
Contributing organizations
Related projects
- Haloniumsupramolecular Chemistry: New Molecular Machines and Nanoreactors
- Rissanen, Kari
- Research Council of Finland
Ministry reporting: Yes
Reporting Year: 2022
JUFO rating: 1