A1 Journal article (refereed)
Expansion and Compression of a Helicate with Central Diol-Units as Stereocontrolling Moieties (2022)

Grüninger, S., Mevissen, C., Ward, J. S., Rissanen, K., & Albrecht, M. (2022). Expansion and Compression of a Helicate with Central Diol-Units as Stereocontrolling Moieties. Organic Materials, 4(4), 277-280. https://doi.org/10.1055/a-1945-0582

JYU authors or editors

Publication details

All authors or editors: Grüninger, Saskia; Mevissen, Christian; Ward, Jas S.; Rissanen, Kari; Albrecht, Markus

Journal or series: Organic Materials

eISSN: 2625-1825

Publication year: 2022

Publication date: 15/09/2022

Volume: 4

Issue number: 4

Pages range: 277-280

Publisher: Georg Thieme Verlag KG

Publication country: Germany

Publication language: English

DOI: https://doi.org/10.1055/a-1945-0582

Publication open access: Openly available

Publication channel open access: Open Access channel

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/84491

Abstract

The dicatechol ester ligand 2-H4 forms the compressed helicate Li4[(2)3Ti2] which upon removal of the internally bound lithium cations expands. In the compressed form, the chiral diol units control the stereochemistry of the complex which is lost upon expansion of the system.

Keywords: supramolecular chemistry; nanotechnology; coordination complexes; molecules; metals; lithium; cations

Free keywords: self-assembly; helicate; molecular switch; stereochemistry

Contributing organizations

Ministry reporting: Yes

VIRTA submission year: 2022

JUFO rating: 1