A1 Journal article (refereed)
The solid-state hierarchy and iodination potential of [bis(3-acetaminopyridine)iodine(I)]PF6 (2022)

Ward, J. S. (2022). The solid-state hierarchy and iodination potential of [bis(3-acetaminopyridine)iodine(I)]PF6. CrystEngComm, 24(40), 7029-7033. https://doi.org/10.1039/d2ce01225a

JYU authors or editors

Ward, James

Publication details

All authors or editors: Ward, Jas S.

Journal or series: CrystEngComm

eISSN: 1466-8033

Publication year: 2022

Volume: 24

Issue number: 40

Pages range: 7029-7033

Publisher: Royal Society of Chemistry (RSC)

Publication country: United Kingdom

Publication language: English

DOI: https://doi.org/10.1039/d2ce01225a

Publication open access: Openly available

Publication channel open access: Partially open access channel

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/84694

Abstract

The first iodine(I) complex bearing hydrogen-bond donor and acceptor groups, [bis(3-acetaminopyridine)iodine(I)]PF6 (3), was synthesised, which exhibited two temperature-dependent solid-state connectivities of the hydrogen bonding. Upon reaction of 3 with tBuOMe, unprecedented iodination of a tBu methyl group proceeded under exceptionally mild conditions in good yield.

Keywords: chemistry; solid-state chemistry; hydrogen bonds; iodine

Free keywords: solid-state chemistry; iodine

Fields of science: