A1 Journal article (refereed)
Selective gas adsorption by calixarene-based porous octahedral M32 coordination cages (2022)

Khariushin, I., Ovsyannikov, A., Baudron, S., Ward, J., Kiesilä, A., Rissanen, K., Kalenius, E., Kovalenko, K., Fedin, V., Solovieva, S., Antipin, I., Bulach, V., & Ferlay, S. (2022). Selective gas adsorption by calixarene-based porous octahedral M32 coordination cages. Chemical Communications, 58(98), 13628-13631. https://doi.org/10.1039/d2cc04510a

JYU authors or editors

Ward, James
Kiesilä, Anniina
Rissanen, Kari
Kalenius, Elina

Publication details

All authors or editors: Khariushin, Ivan, V.; Ovsyannikov, Alexander, S.; Baudron, Stéphane, A.; Ward, Jas, S.; Kiesilä, Anniina; Rissanen, Kari; Kalenius, Elina; Kovalenko, Konstantin, A.; Fedin, Vladimir, P.; Solovieva, Svetlana, E.; et al.

Journal or series: Chemical Communications

ISSN: 1359-7345

eISSN: 1364-548X

Publication year: 2022

Publication date: 15/11/2022

Volume: 58

Issue number: 98

Pages range: 13628-13631

Publisher: Royal Society of Chemistry (RSC)

Publication country: United Kingdom

Publication language: English

DOI: https://doi.org/10.1039/d2cc04510a

Publication open access: Openly available

Publication channel open access: Partially open access channel

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/84310

Abstract

Giant octahedral M32 coordination cages were prepared via self-assembly of sulfonylcalix[4]arene-supported tetranuclear M(II) clusters (M = Co, Ni) with hybrid linker based on tris(dipyrrinato)cobalt(III) complexes appended with peripherical carboxylic groups. Due to intrinsic and extrinsic porosity, the obtained solid-state supramolecular architectures demonstrated good performance as adsorbents for the separation of industrially important gases mixtures.

Keywords: supramolecular chemistry; coordination complexes; cobalt; carboxylic acids; porosity; adsorption; gases