A2 Review article, Literature review, Systematic review
Biomass-derived carbon–silicon composites (C@Si) as anodes for lithium-ion and sodium-ion batteries : A promising strategy towards long-term cycling stability : A mini review (2023)


Simoes dos Reis, G., Molaiyan, P., Subramaniyam, C. M., García-Alvarado, F., Paolella, A., Pequeno de Oliveira, H., & Lassi, U. (2023). Biomass-derived carbon–silicon composites (C@Si) as anodes for lithium-ion and sodium-ion batteries : A promising strategy towards long-term cycling stability : A mini review. Electrochemistry Communications, 153, Article 107536. https://doi.org/10.1016/j.elecom.2023.107536


JYU authors or editors


Publication details

All authors or editorsSimoes dos Reis, Glaydson; Molaiyan, Palanivel; Subramaniyam, Chandrasekar M.; García-Alvarado, Flaviano; Paolella, Andrea; Pequeno de Oliveira, Helinando; Lassi, Ulla

Journal or seriesElectrochemistry Communications

ISSN1388-2481

eISSN1873-1902

Publication year2023

Publication date06/07/2023

Volume153

Article number107536

PublisherElsevier BV

Publication countryUnited States

Publication languageEnglish

DOIhttps://doi.org/10.1016/j.elecom.2023.107536

Publication open accessOpenly available

Publication channel open accessOpen Access channel

Publication is parallel published (JYX)https://jyx.jyu.fi/handle/123456789/88787

Publication is parallel publishedhttps://res.slu.se/id/publ/122634


Abstract

The global need for high energy density and performing rechargeable batteries has led to the development of high-capacity silicon-based anode materials to meet the energy demands imposed to electrify plug-in vehicles to curtail carbon emissions by 2035. Unfortunately, the high theoretical capacity (4200 mA h g− 1) of silicon by (de-)alloy mechanism is limited by its severe volume changes (ΔV ~ 200% − 400%) during cycling for lithium-ion batteries (LIBs), while for sodium-ion batteries (NIBs) remain uncertain, and hence, compositing with carbons (C@Si) represent a promising strategy to enable the aforementioned practical application. The present review outlines the recent progress of biomass-derived Si-carbon composite (C@Si) anodes for LIBs and NIBs. In this perspective, we present different types of biomass precursors, silicon sources, and compositing strategies, and how these impact on the C@Si physicochemical properties and their electrochemical performance are discussed.


Keywordscarbonbiomass (industry)biocharsiliconcompositesaccumulatorsvehiclescapacityrecyclingecological sustainability

Free keywordsbiomass carbon; biobased-silicon; silicon-carbon anodes; volume expansion; sustainable batteries


Contributing organizations


Related projects

  • GreenBattery
      • AsplundTina
    • European Commission
    01/01/2023-31/12/2025


Ministry reportingYes

Reporting Year2023

Preliminary JUFO rating1


Last updated on 2024-03-04 at 18:46