A2 Review article, Literature review, Systematic review
Biomass-derived carbon–silicon composites (C@Si) as anodes for lithium-ion and sodium-ion batteries : A promising strategy towards long-term cycling stability : A mini review (2023)
Simoes dos Reis, G., Molaiyan, P., Subramaniyam, C. M., García-Alvarado, F., Paolella, A., Pequeno de Oliveira, H., & Lassi, U. (2023). Biomass-derived carbon–silicon composites (C@Si) as anodes for lithium-ion and sodium-ion batteries : A promising strategy towards long-term cycling stability : A mini review. Electrochemistry Communications, 153, Article 107536. https://doi.org/10.1016/j.elecom.2023.107536
JYU authors or editors
Publication details
All authors or editors: Simoes dos Reis, Glaydson; Molaiyan, Palanivel; Subramaniyam, Chandrasekar M.; García-Alvarado, Flaviano; Paolella, Andrea; Pequeno de Oliveira, Helinando; Lassi, Ulla
Journal or series: Electrochemistry Communications
ISSN: 1388-2481
eISSN: 1873-1902
Publication year: 2023
Publication date: 06/07/2023
Volume: 153
Article number: 107536
Publisher: Elsevier BV
Publication country: United States
Publication language: English
DOI: https://doi.org/10.1016/j.elecom.2023.107536
Publication open access: Openly available
Publication channel open access: Open Access channel
Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/88787
Publication is parallel published: https://res.slu.se/id/publ/122634
Abstract
The global need for high energy density and performing rechargeable batteries has led to the development of high-capacity silicon-based anode materials to meet the energy demands imposed to electrify plug-in vehicles to curtail carbon emissions by 2035. Unfortunately, the high theoretical capacity (4200 mA h g− 1) of silicon by (de-)alloy mechanism is limited by its severe volume changes (ΔV ~ 200% − 400%) during cycling for lithium-ion batteries (LIBs), while for sodium-ion batteries (NIBs) remain uncertain, and hence, compositing with carbons (C@Si) represent a promising strategy to enable the aforementioned practical application. The present review outlines the recent progress of biomass-derived Si-carbon composite (C@Si) anodes for LIBs and NIBs. In this perspective, we present different types of biomass precursors, silicon sources, and compositing strategies, and how these impact on the C@Si physicochemical properties and their electrochemical performance are discussed.
Keywords: carbon; biomass (industry); biochar; silicon; composites; accumulators; vehicles; capacity; recycling; ecological sustainability
Free keywords: biomass carbon; biobased-silicon; silicon-carbon anodes; volume expansion; sustainable batteries
Contributing organizations
Related projects
- GreenBattery
- Asplund, Tina
- European Commission
Ministry reporting: Yes
VIRTA submission year: 2023
JUFO rating: 1