A1 Journal article (refereed)
Strontium Complexes of CAlixarene Amides in the Solid State: Structural Dependence on the Ligand Size and Counter Ions (2000)


Rissanen, K., Casnati, A., Pelizzi, N., Baldini, L., Ugozzoli, F., & Ungaro, R. (2000). Strontium Complexes of CAlixarene Amides in the Solid State: Structural Dependence on the Ligand Size and Counter Ions. Journal of Chemical Society, Dalton Transactions, 2000(19), 3411-3415. https://doi.org/10.1039/B004402O


JYU authors or editors


Publication details

All authors or editors: Rissanen, Kari; Casnati, Alessandro; Pelizzi, Nicola; Baldini, Laura; Ugozzoli, Franco; Ungaro, Rocco

Journal or series: Journal of Chemical Society, Dalton Transactions

Publication year: 2000

Volume: 2000

Issue number: 19

Pages range: 3411-3415

Publication country: United Kingdom

Publication language: English

DOI: https://doi.org/10.1039/B004402O

Publication open access: Not open

Publication channel open access:


Abstract

For the first time, crystal structures of three strontium complexes of calixarene amides have been determined. A p-tert-butylcalix[6]arene hexaamide forms a 1∶1 complex with Sr(Pic)2 (Pic = picrate), whereas p-tert-butylcalix[8]arene and p-methoxycalix[8]arene octaamides encapsulate two strontium cations each. The binding geometries of the metal cations depend on the ligand size and on the counter anion used (chloride or picrate).



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