A1 Journal article (refereed)
Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions : Direct Synthesis of N‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones (2024)


Pan, S., Mulks, F., Wu, P., Rissanen, K., & Bolm, C. (2024). Mechanochemical Iron‐Catalyzed Nitrene Transfer Reactions : Direct Synthesis of N‐Acyl Sulfonimidamides from Sulfinamides and Dioxazolones. Angewandte Chemie, 63(5), Article e202316702. https://doi.org/10.1002/anie.202316702


JYU authors or editors


Publication details

All authors or editorsPan, Shulei; Mulks, Florian; Wu, Peng; Rissanen, Kari; Bolm, Carsten

Journal or seriesAngewandte Chemie

ISSN1433-7851

eISSN1521-3773

Publication year2024

Publication date06/12/2023

Volume63

Issue number5

Article numbere202316702

PublisherWiley-VCH Verlag

Publication countryGermany

Publication languageEnglish

DOIhttps://doi.org/10.1002/anie.202316702

Publication open accessOpenly available

Publication channel open accessPartially open access channel

Publication is parallel published (JYX)https://jyx.jyu.fi/handle/123456789/93512

Additional informationCommunication


Abstract

A mechanochemical synthesis of sulfonimidamides by iron(II)-catalyzed exogenous ligand-free N-acyl nitrene transfer to sulfinamides is reported. The one-step method tolerates a wide range of sulfinamides with various substituents under solvent-free ambient conditions. Compared to its solution-phase counterpart, this mechanochemical approach shows better conversion and chemoselectivity. Mechanistic investigations by ESI-MS revealed the generation of crucial nitrene iron intermediates.


Keywordssulphur compoundsnitrogen compoundschemical synthesiscatalysis


Contributing organizations


Ministry reportingYes

Reporting Year2023

JUFO rating3


Last updated on 2024-15-06 at 21:46