A1 Journal article (refereed)
Unexpected self-assembly of a homochiral metallosupramolecular M4L4 catenane (2014)
Hovorka, Rainer; Meyer-Eppler, Georg; Piehler, Torsten; Hytteballe, Sophie; Engeser, Marianne; Topic, Filip; Rissanen, Kari; Lützen, Arne (2014). Unexpected self-assembly of a homochiral metallosupramolecular M4L4 catenane. Chemistry: A European Journal, 20 (41), 13253–13258. DOI: 10.1002/chem.201403414
JYU authors or editors
Publication details
All authors or editors: Hovorka, Rainer; Meyer-Eppler, Georg; Piehler, Torsten; Hytteballe, Sophie; Engeser, Marianne; Topic, Filip; Rissanen, Kari; Lützen, Arne
Journal or series: Chemistry: A European Journal
ISSN: 0947-6539
eISSN: 1521-3765
Publication year: 2014
Volume: 20
Issue number: 41
Pages range: 13253–13258
Publisher: Wiley - V C H Verlag GmbH & Co. KGaA
Publication country: Germany
Publication language: English
DOI: https://doi.org/10.1002/chem.201403414
Open Access: Publication channel is not openly available
Abstract
Two enantiomerically pure 9,9′‐spirobifluorene‐based bis(pyridine) ligands 1 and 2 were prepared to study their self‐assembly behavior upon coordination to cis‐protected palladium(II) ions. Whereas the sterically more demanding ligand, 2, gave rise to the expected dinuclear metallosupramolecular M2L2 rhombi, the sterically less demanding ligand, 1, acts as a template to give rise to a homochiral metallosupramolecular M4L4 catenane.
Free keywords: 9; 9'-spirobifluorenes; catenanes; metallosupramolecular chemistry; palladium complexes; self-assembly
Contributing organizations
Related projects
- Weak Interactions as Structural Elements in Self-assembling Molecular Systems
- Rissanen, Kari
- Academy of Finland
Ministry reporting: Yes
Reporting Year: 2014
JUFO rating: 3