A1 Journal article (refereed)
Face-controlled chirality induction in octahedral thiacalixarene-based porous coordination cages (2025)

Khariushin, I. V., Ovsyannikov, A. S., Baudron, S. A., Ward, J. S., Kiesilä, A., Rissanen, K., Kalenius, E., Chessé, M., Nowicka, B., Solovieva, S. E., Antipin, I. S., Bulach, V., & Ferlay, S. (2025). Face-controlled chirality induction in octahedral thiacalixarene-based porous coordination cages. Nanoscale, Early online. https://doi.org/10.1039/d4nr03622k

JYU authors or editors

Publication details

All authors or editors: Khariushin, Ivan V.; Ovsyannikov, Alexander S.; Baudron, Stéphane A.; Ward, Jas S.; Kiesilä, Anniina; Rissanen, Kari; Kalenius, Elina; Chessé, Matthieu; Nowicka, Beata; Solovieva, Svetlana E.; et al.

Journal or series: Nanoscale

ISSN: 2040-3364

eISSN: 2040-3372

Publication year: 2025

Publication date: 09/12/2024

Volume: Early online

Publisher: Royal Society of Chemistry

Publication country: United Kingdom

Publication language: English

DOI: https://doi.org/10.1039/d4nr03622k

Publication open access: Not open

Publication channel open access: 

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/99064

Abstract

Nanosized chiral octahedral M32 coordination cages were prepared via self-assembly of sulfonylcalix[4]arene tetranuclear M(II) clusters (M = Co or Ni) with enantiomerically enriched linkers based on tris(dipyrrinato)cobalt(III) complexes, appended with peripheral carboxylic groups. Two pairs of enantiomers of cages were obtained and unambiguously characterized from a structural point of view, using single crystal X-ray diffraction. Chiral-HPLC was used to evidence the enantiomers. In the solid state, the compounds present intrinsic and extrinsic porosity: the intrinsic porosity is linked with the size of the cages, which present an inner diameter of ca. 19 Å. The obtained solid-state supramolecular architectures demonstrated good performances as adsorbents for water and 2-butanol guest molecules.

Keywords: supramolecular chemistry; coordination complexes; nanostructures

Contributing organizations

Ministry reporting: Yes

VIRTA submission year: 2025

Preliminary JUFO rating: 3