A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
Recognition oxovanadium(V) species and its separation from other metal species through selective complexation by some acyclic ligands (1998)
Rao, C. P., Sreedhara, A., Rao, P., Lokanath, N., Sridhar, M., Prasad, J., & Rissanen, K. (1998). Recognition oxovanadium(V) species and its separation from other metal species through selective complexation by some acyclic ligands. Polyhedron, 18(1-2), 289-297. https://doi.org/10.1016/S0277-5387(98)00298-8
JYU-tekijät tai -toimittajat
Julkaisun tiedot
Julkaisun kaikki tekijät tai toimittajat: Rao, Chebrolu P.; Sreedhara, A.; Rao, P.Venkateswara; Lokanath, N.K.; Sridhar, M.a.; Prasad, J.S.; Rissanen, Kari
Lehti tai sarja: Polyhedron
ISSN: 0277-5387
eISSN: 1873-3719
Julkaisuvuosi: 1998
Volyymi: 18
Lehden numero: 1-2
Artikkelin sivunumerot: 289-297
Kustantaja: Elsevier
Julkaisumaa: Britannia
Julkaisun kieli: englanti
DOI: https://doi.org/10.1016/S0277-5387(98)00298-8
Julkaisun avoin saatavuus: Ei avoin
Julkaisukanavan avoin saatavuus:
Tiivistelmä
Acyclic molecules possessing -OH (phenoxo and alkoxo type) groups and imine or amine moieties have been developed to sense the specific preference for VO3+ species. These molecules also showed a capability to quantitatively separate oxovanadium(V) species from a reaction mixture containing metal species of V, Mo, U, Fe, and Mn ions in solution. A cascade quantitative separation of VO3+ followed by cis-MoO2+2 followed by trans UO2+2 species is demonstrated from their mixture. Synthesis and structural details of oxo-species of vanadium molybdenum and uranium are also discussed. Factors influencing the complexation of these molecules towards oxo metal species of V, Mo and U are also addressed.
Vapaat asiasanat: kiderakenne
Liittyvät organisaatiot
OKM-raportointi: Kyllä
Alustava JUFO-taso: Not rated
