A1 Journal article (refereed)
N-Alkyl ammonium resorcinarene polyiodides (2016)


Pan, F., Beyeh, N. K., Ras, R. H. A., & Rissanen, K. (2016). N-Alkyl ammonium resorcinarene polyiodides. CrystEngComm, 18 (30), 5724-5727. doi:10.1039/C6CE01229A


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Publication details

All authors or editors: Pan, Fangfang; Beyeh, Ngong Kodiah; Ras, Robin H. A.; Rissanen, Kari

Journal or series: CrystEngComm

ISSN: 1466-8033

eISSN: 1466-8033

Publication year: 2016

Volume: 18

Issue number: 30

Pages range: 5724-5727

Publisher: Royal Society of Chemistry

Publication country: United Kingdom

Publication language: English

DOI: https://doi.org/10.1039/C6CE01229A

Open Access: Publication channel is not openly available


Abstract

Four N-alkyl ammonium resorcinarene halides incorporating polyiodides were obtained and structurally analyzed by single crystal X-ray crystallography. The unexpected formation of triiodides and pentaiodide anions in these structures was assumed to be the result of the heterolytic dissociation of molecular iodine (I2) in the presence of electron donors in the N-alkyl ammonium resorcinarene halide system, from which I− further binds one or two I2 molecules resulting in I3− or I5− species, respectively.


Free keywords: N-Alkyl ammonium; polyiodides


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Ministry reporting: Yes

Reporting Year: 2016

JUFO rating: 1


Last updated on 2020-17-10 at 20:25