A1 Journal article (refereed)
N-Alkyl ammonium resorcinarene polyiodides (2016)
Pan, F., Beyeh, N. K., Ras, R. H. A., & Rissanen, K. (2016). N-Alkyl ammonium resorcinarene polyiodides. CrystEngComm, 18 (30), 5724-5727. doi:10.1039/C6CE01229A
JYU authors or editors
Publication details
All authors or editors: Pan, Fangfang; Beyeh, Ngong Kodiah; Ras, Robin H. A.; Rissanen, Kari
Journal or series: CrystEngComm
ISSN: 1466-8033
eISSN: 1466-8033
Publication year: 2016
Volume: 18
Issue number: 30
Pages range: 5724-5727
Publisher: Royal Society of Chemistry
Publication country: United Kingdom
Publication language: English
DOI: https://doi.org/10.1039/C6CE01229A
Open Access: Publication channel is not openly available
Abstract
Four N-alkyl ammonium resorcinarene halides incorporating polyiodides were obtained and structurally analyzed by single crystal X-ray crystallography. The unexpected formation of triiodides and pentaiodide anions in these structures was assumed to be the result of the heterolytic dissociation of molecular iodine (I2) in the presence of electron donors in the N-alkyl ammonium resorcinarene halide system, from which I− further binds one or two I2 molecules resulting in I3− or I5− species, respectively.
Free keywords: N-Alkyl ammonium; polyiodides
Contributing organizations
Related projects
- Weak Interactions as Structural Elements in Self-assembling Molecular Systems
- Rissanen, Kari
- Academy of Finland
- Weak Interactions as Structural Elements in Self-assembling Molecular Systems (research costs)
- Rissanen, Kari
- Academy of Finland
Ministry reporting: Yes
Reporting Year: 2016
JUFO rating: 1
