A1 Journal article (refereed)
Capturing Hydrophobic Trifluoroiodomethane in Water into an M4L6 Cage (2016)


Giri, C., Sahoo, P. K., Rissanen, K., & Mal, P. (2016). Capturing Hydrophobic Trifluoroiodomethane in Water into an M4L6 Cage. European Journal of Inorganic Chemistry, 2016 (31), 4964-4967. doi:10.1002/ejic.201600990


JYU authors or editors


Publication details

All authors or editors: Giri, Chandan; Sahoo, Prasit Kumar; Rissanen, Kari; Mal, Prasenjit

Journal or series: European Journal of Inorganic Chemistry

ISSN: 1434-1948

eISSN: 1099-0682

Publication year: 2016

Volume: 2016

Issue number: 31

Pages range: 4964-4967

Publisher: Wiley - V C H Verlag GmbH & Co. KGaA

Place of Publication: Weinheim

Publication country: Germany

Publication language: English

DOI: https://doi.org/10.1002/ejic.201600990

Open Access: Publication channel is not openly available

Additional information: Communication.


Abstract

Synthetically important trifluoroiodomethane (CF3I) was trapped in water by using a metal–organic supramolecular anionic cage. Under ambient conditions, nearly 1:1 encapsulation of the hydrophobic, gaseous CF3I substrate with the cage was observed, and its binding constant was calculated by relative comparison with benzene encapsulation.


Keywords: chemistry; water

Free keywords: Hydrophobic Trifluoroiodomethane; metal–organic frameworks


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Related projects


Ministry reporting: Yes

Reporting Year: 2016

JUFO rating: 1


Last updated on 2020-17-10 at 21:06