A1 Journal article (refereed)
Electron-deficient trifluoromethyl-substituted sub-components affect the properties of M4L4 tetrahedral cages (2017)

Struch, N., Topic, F., Rissanen, K., & Lützen, A. (2017). Electron-deficient trifluoromethyl-substituted sub-components affect the properties of M4L4 tetrahedral cages. Dalton Transactions, 46 (33), 10809-10813. doi:10.1039/C7DT02182H

JYU authors or editors

Publication details

All authors or editors: Struch, Niklas; Topic, Filip; Rissanen, Kari; Lützen, Arne

Journal or series: Dalton Transactions

ISSN: 1477-9226

eISSN: 1477-9234

Publication year: 2017

Volume: 46

Issue number: 33

Pages range: 10809-10813

Publisher: Royal Society of Chemistry

Publication country: United Kingdom

Publication language: English

DOI: https://doi.org/10.1039/C7DT02182H

Open Access: Publication channel is not openly available

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/55225

Abstract

Two supramolecular tetrahedral cages based on a new electron-deficient trifluoromethyl-substituted pyridylimine ligand are synthesised by sub-component self-assembly. Their structures are characterised by NMR und UV-Vis spectroscopy, high-resolution mass spectrometry and single crystal X-ray diffraction. The iron(II) complex shows host–guest chemistry, complex-to-complex transformations and novel electronic properties.

Free keywords: electron-deficient trifluoromethyl-substituted sub-components

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