A1 Journal article (refereed)
Small Hydrocarbon Cyclophanes : Synthesis, X-ray Analysis and Molecular Modeling (2002)
Lahtinen, T., Wegelius, E., Linnanto, J., & Rissanen, K. (2002). Small Hydrocarbon Cyclophanes : Synthesis, X-ray Analysis and Molecular Modeling. European Journal of Organic Chemistry, 2002(17), 2935-2941. https://doi.org/10.1002/1099-0690(200209)2002:17<2935::AID-EJOC2935>3.0.CO;2-Y
JYU authors or editors
Publication details
All authors or editors: Lahtinen, Tanja; Wegelius, Elina; Linnanto, Juha; Rissanen, Kari
Journal or series: European Journal of Organic Chemistry
ISSN: 1434-193X
eISSN: 1099-0690
Publication year: 2002
Volume: 2002
Issue number: 17
Pages range: 2935-2941
Publisher: Wiley
Publication country: Germany
Publication language: English
Publication open access: Not open
Publication channel open access:
Abstract
Small hydrocarbon cyclophanes, such as [2.2.0]m,m,m-cyclophane (20) and [2.2.0]p,m,m-cyclophane (21), are strained analogues of the well-known π-prismand [2.2.2]p,p,p-cyclophane (1). The synthetic route to these molecules is based on well-established cyclophane methodology which offers a general access to a whole family of hydrocarbon cyclophanes. Single crystal X-ray analysis and molecular modelling showed that the reduction of the ring size from 18-membered (1) to 14-membered (21) or 13-membered (20) has a substantial effect on the size and the shape of the cyclophane’s cavity, thus blocking its ability to complex Ag+ ions. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)
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