A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
Self-Complementary Dimers of Oxalamide-Functionalized Resorcinarene Tetrabenzoxazines (2018)

Dzolic, Z., Beyeh, N. K., Cetina, M., Turunen, L., & Rissanen, K. (2018). Self-Complementary Dimers of Oxalamide-Functionalized Resorcinarene Tetrabenzoxazines. Chemistry: An Asian Journal, 13(2), 164-169. https://doi.org/10.1002/asia.201701426

JYU-tekijät tai -toimittajat

Dzolic, Zoran
Turunen, Lotta
Rissanen, Kari

Julkaisun tiedot

Julkaisun kaikki tekijät tai toimittajat: Dzolic, Zoran; Beyeh, Ngong Kodiah; Cetina, Mario; Turunen, Lotta; Rissanen, Kari

Lehti tai sarja: Chemistry: An Asian Journal

ISSN: 1861-4728

eISSN: 1861-471X

Julkaisuvuosi: 2018

Volyymi: 13

Lehden numero: 2

Artikkelin sivunumerot: 164-169

Kustantaja: Wiley-VCH Verlag

Kustannuspaikka: Weinheim

Julkaisumaa: Saksa

Julkaisun kieli: englanti

DOI: https://doi.org/10.1002/asia.201701426

Julkaisun avoin saatavuus: Ei avoin

Julkaisukanavan avoin saatavuus:

Julkaisu on rinnakkaistallennettu (JYX): https://jyx.jyu.fi/handle/123456789/56809

Tiivistelmä

Self‐complementarity is a useful concept in supramolecular chemistry, molecular biology and polymeric systems. Two resorcinarene tetrabenzoxazines decorated with four oxalamide groups were synthesized and characterized. The oxalamide groups possessed self‐complementary hydrogen bonding sites between the carbonyls and amide groups. The self‐complementary nature of the oxalamide groups resulted in self‐included dimeric assemblies. The hydrogen bonding interactions within the tetrabenzoxazines gave rise to the formation of dimers, which were confirmed by single‐crystal X‐ray diffractions analysis and supported by NMR spectroscopy and mass spectrometry. The self‐included dimers were connected by numerous and strong intermolecular N−H⋅⋅⋅O and C−H⋅⋅⋅O hydrogen bonds supplemented with C−H⋅⋅⋅π interactions, forming one‐dimensional polymers, which were then further linked into three‐dimensional networks.

YSO-asiasanat: oligomeeri; karbonyylit; amidit; spektroskopia; massaspektrometria; vety; obligaatiot