A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
Bamboo-like Chained Cavities and Other Halogen-Bonded Complexes from Tetrahaloethynyl Cavitands with Simple Ditopic Halogen Bond Acceptors (2018)
Turunen, L., Pan, F., Beyeh, N. K., Trant, J. F., Ras, R. H. A., & Rissanen, K. (2018). Bamboo-like Chained Cavities and Other Halogen-Bonded Complexes from Tetrahaloethynyl Cavitands with Simple Ditopic Halogen Bond Acceptors. Crystal Growth and Design, 18(1), 513-520. https://doi.org/10.1021/acs.cgd.7b01517
JYU-tekijät tai -toimittajat
Julkaisun tiedot
Julkaisun kaikki tekijät tai toimittajat: Turunen, Lotta; Pan, FangFang; Beyeh, Ngong Kodiah; Trant, John F.; Ras, Robin H. A.; Rissanen, Kari
Lehti tai sarja: Crystal Growth and Design
ISSN: 1528-7483
eISSN: 1528-7505
Julkaisuvuosi: 2018
Volyymi: 18
Lehden numero: 1
Artikkelin sivunumerot: 513-520
Kustantaja: American Chemical Society
Kustannuspaikka: Washington
Julkaisumaa: Yhdysvallat (USA)
Julkaisun kieli: englanti
DOI: https://doi.org/10.1021/acs.cgd.7b01517
Julkaisun avoin saatavuus: Ei avoin
Julkaisukanavan avoin saatavuus:
Julkaisu on rinnakkaistallennettu (JYX): https://jyx.jyu.fi/handle/123456789/56817
Tiivistelmä
Halogen bonding provides a useful complement to hydrogen bonding and metal-coordination as a tool for organizing supramolecular systems. Resorcinarenes, tetrameric bowl-shaped cavitands, have been previously shown to function as efficient scaffolds for generating dimeric capsules in both solution and solid-phase, and complicated one-, two-, and three-dimensional frameworks in the solid phase. Tetrahaloethynyl resorcinarenes (bromide and iodide) position the halogen atoms in a very promising “crown-like” orientation for acting as organizing halogen-bond donors to help build capsules and higher-order networks. Symmetric divalent halogen bond acceptors including bipyridines, 1,4-dioxane, and 1,4-diazabicyclo[2.2.2]octane are very promising halogen bond accepting partners for creating these systems. This report describes the complex structures arising from combining these various systems including self-included dimers, herringbone-packed architectures enclosing medium (186 Å3) cavities, and a very intriguing bamboo-like one-dimensional rod with large (683 Å3) cavities between adjacent dimeric units. These various structures, all organized through host–host, host–acceptor, and host–solvent interactions highlight the emergent complexity of these types of complexes. As halogen bonds are weaker than hydrogen-bonds, the resulting architectures are harder to predict, and these results provide additional insight into the parameters requiring consideration when designing crystalline supramolecular systems using halogen-bonds as the core organizing principle.
YSO-asiasanat: halogeenit; obligaatiot; kemia
Vapaat asiasanat: halogen-bonded complexes; halogen bonds
Liittyvät organisaatiot
Hankkeet, joissa julkaisu on tehty
- Heikot vuorovaikutukset itsejärjestäytyvien molekyylisysteemien rakenneosina
- Rissanen, Kari
- Suomen Akatemia
- Heikot vuorovaikutukset itsejärjestäytyvien molekyylisysteemien rakenneosina (tutkimuskulut)
- Rissanen, Kari
- Suomen Akatemia
OKM-raportointi: Kyllä
Raportointivuosi: 2018
JUFO-taso: 2