A1 Journal article (refereed)
Ligand Entrapment in Twofold Interpenetrating PtS Matrices by Metallo-Organic Frameworks (2003)

Nättinen, K., & Rissanen, K. (2003). Ligand Entrapment in Twofold Interpenetrating PtS Matrices by Metallo-Organic Frameworks. Inorganic Chemistry, 42(7), 5126-5134. https://doi.org/10.1021/ic034246r

JYU authors or editors

Publication details

All authors or editors: Nättinen, Kalle; Rissanen, Kari

Journal or series: Inorganic Chemistry

Publication year: 2003

Volume: 42

Issue number: 7

Pages range: 5126-5134

Publication country: United States

Publication language: English

DOI: https://doi.org/10.1021/ic034246r

Publication open access: Not open

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Abstract

Single-crystal X-ray crystallography was used to determine the structures of four metallo-organic frameworks (MOFs). A dendritic tetradentate ligand (tetrakis(isonicotinoxymethyl)methane, TINM) was used with first-row transition-metal elements copper, nickel, and cobalt to synthesize MOFs with a PtS interpenetration, due to both planar and tetrahedral junctions being present in the framework. Two different polymeric complexes, 1 and 2, were obtained from similar starting materials, TINM and Cu(NO3)2·3H2O, but different solvents. The use of dichloromethane in addition to methanol and water promoted the coordination of nitrate ions to the copper. With only methanol and water used as solvent, the copper atom was coordinated to water molecules instead. Compound 1 has pores going through the structure in two dimensions, along crystallographic axes a and c with diameters of the pores (the diameters correspond to the minimum distances between van der Waals surfaces of opposing walls defined by projection along channel axis) approximately 1.0 × 3.1 and 2.5 × 3.7 Å, respectively. Compound 2 has channels along all crystallographic axes. The dimensions of the channels are 3.2 × 3.7, 3.7 × 5.0, and 2.8 × 4.1 Å, respectively. The structures of 3 and 4 entrap a large guest ligand molecule in the framework. The guest ligand is uncoordinated, although the pattern that the entrapped guests form brings the two arms of any two guests within close range. The lack of 3-fold penetration is due to only two arms being close to each other and also the fact that there is no space for an additional set of metal centers.

Free keywords: Metalloorganic frameworks; X-ray structure

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