A1 Journal article (refereed)
Time-gated Raman and laser-induced breakdown spectroscopy in mapping of eudialyte and catapleiite (2020)
Romppanen, S., Häkkänen, H., Kekkonen, J., Nissinen, J., Nissinen, I., Kostamovaara, J., & Kaski, S. (2020). Time-gated Raman and laser-induced breakdown spectroscopy in mapping of eudialyte and catapleiite. Journal of Raman Spectroscopy, 51(9), 1462-1469. https://doi.org/10.1002/jrs.5622
JYU authors or editors
Publication details
All authors or editors: Romppanen, Sari; Häkkänen, Heikki; Kekkonen, Jere; Nissinen, Jan; Nissinen, Ilkka; Kostamovaara, Juha; Kaski, Saara
Journal or series: Journal of Raman Spectroscopy
ISSN: 0377-0486
eISSN: 1097-4555
Publication year: 2020
Volume: 51
Issue number: 9
Pages range: 1462-1469
Publisher: John Wiley & Sons Ltd.
Publication country: United Kingdom
Publication language: English
DOI: https://doi.org/10.1002/jrs.5622
Publication open access: Not open
Publication channel open access:
Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/67133
Additional information: Special Issue: GeoRaman 2018.
Abstract
Raman analysis of rock samples containing rare earth elements (REEs) is challenging due to the strong fluorescence, which may mask the weaker Raman signal. In this research, time‐gated (TG) Raman has been applied to the construction of the mineral distribution map from REE‐bearing rock. With TG Raman, material is excited with a short subnanosecond laser pulse, and the Raman signal is collected within a picosecond‐scale time window prior to the formation of a strong fluorescent signal by means of single‐photon avalanche diode array. This allows signal readout with a significantly reduced fluorescence background. TG Raman maps are used to reveal the location of valuable minerals and are compared with the elemental distribution given by laser‐induced breakdown spectroscopy. The analysis was carried out from a REE‐bearing rock, nepheline syenite sample from the Norra Kärr deposit, where REEs are mainly hosted in eudialyte and catapleiite. The combination of these two complimentary laser spectroscopic methods offers valuable elemental and mineralogical information about rocks.
Keywords: spectroscopy
Free keywords: laser-induced breakdown spectroscopy (LIBS); mineral mapping; REE&-bearing minerals; rock analysis; time-gated Raman
Contributing organizations
Related projects
- Rapid analysis of minerals and rare earth elements by time-gated laser spectroscopy
- Kaski, Saara
- Research Council of Finland
- Rapid analysis of minerals and rare earth elements y time-gated laser spectroscopy - LasaREE
- Häkkänen, Heikki
- Research Council of Finland
Ministry reporting: Yes
Reporting Year: 2020
JUFO rating: 1