A1 Journal article (refereed)
Selective Recognition of Phenazine by 2,6‐Dibutoxylnaphthalene‐Based Tetralactam Macrocycle (2019)
Wang, Li‐Li; Tu, Yi‐Kuan; Valkonen, Arto; Rissanen, Kari; Jiang, Wei (2019). Selective Recognition of Phenazine by 2,6‐Dibutoxylnaphthalene‐Based Tetralactam Macrocycle. Chinese Journal of Chemistry, 37 (9), 892-896. DOI: 10.1002/cjoc.201900233
JYU authors or editors
Publication details
All authors or editors: Wang, Li‐Li; Tu, Yi‐Kuan; Valkonen, Arto; Rissanen, Kari; Jiang, Wei
Journal or series: Chinese Journal of Chemistry
ISSN: 1001-604X
eISSN: 1614-7065
Publication year: 2019
Volume: 37
Issue number: 9
Pages range: 892-896
Publisher: Science Press; Wiley-VCH Verlag
Publication country: China
Publication language: English
DOI: https://doi.org/10.1002/cjoc.201900233
Open Access: Publication channel is not openly available
Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/65097
Abstract
A 2,6‐dibutoxylnaphthalene‐based tetralactam macrocycle was designed and synthesized. This macrocycle shows highly selective recognition to phenazine ‐‐ a well‐known secondary metabolite in bacteria and an emerging disinfection byproduct in drinking water. In contrast, the macrocycle shows no binding to the structurally similar dibenzo‐1,4‐dioxin. It was revealed that hydrogen bonding, π‐π and σ‐π interactions are the major driving forces between phenazine and the new tetralactam macrocycle. A perfect complementarity in electrostatic potential surfaces may explain the high selectivity. In addition, the macrocycle shows fluorescent response to phenazine, demonstrating its potential in fluorescent detection of phenazine.
Free keywords: polyaromatic hydrocarbon
Contributing organizations
Related projects
- Robust S...I+...S Halogen Bonded Supramolecular Assemblies (research costs)
- Valkonen, Arto
- Academy of Finland
Ministry reporting: Yes
Reporting Year: 2019
JUFO rating: 1