A1 Journal article (refereed)
Fabrication of Porous Hydrogenation Catalysts by a Selective Laser Sintering 3D Printing Technique (2019)


Lahtinen, Elmeri; Turunen, Lotta; Hänninen, Mikko M.; Kolari, Kalle; Tuononen, Heikki M.; Haukka, Matti (2019). Fabrication of Porous Hydrogenation Catalysts by a Selective Laser Sintering 3D Printing Technique. ACS Omega, 4 (7), 12012-12017. DOI: 10.1021/acsomega.9b00711


JYU authors or editors


Publication details

All authors or editors: Lahtinen, Elmeri; Turunen, Lotta; Hänninen, Mikko M.; Kolari, Kalle; Tuononen, Heikki M.; Haukka, Matti

Journal or series: ACS Omega

eISSN: 2470-1343

Publication year: 2019

Volume: 4

Issue number: 7

Pages range: 12012-12017

Publisher: American Chemical Society

Publication country: United States

Publication language: English

DOI: http://doi.org/10.1021/acsomega.9b00711

Open Access: Publication published in an open access channel

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/65161


Abstract

Three-dimensional selective laser sintering printing was utilized to produce porous, solid objects, in which the catalytically active component, Pd/SiO2, is attached to an easily printable supporting polypropylene framework. Physical properties of the printed objects, such as porosity, were controlled by varying the printing parameters. Structural characterization of the objects was performed by helium ion microscopy, scanning electron microscopy, and X-ray tomography, and the catalytic performance of the objects was tested in the hydrogenation of styrene, cyclohexene, and phenylacetylene. The results show that the selective laser sintering process provides an alternative and effective way to produce highly active and easily reusable heterogeneous catalysts without significantly reducing the catalytic efficiency of the active Pd/SiO2 component. The ability to control the size, porosity, mechanical properties, flow properties, physical properties, and chemical properties of the catalyst objects opens up possibilities to optimize devices for different reaction environments including batch reactions and continuous flow systems.


Keywords: catalysts; 3D printing; porosity

Free keywords: hydrogenation catalysts; fabrication; 3D printing; laser sintering printing


Contributing organizations


Related projects

Functional Metallopolymers
Haukka, Matti
Academy of Finland
01/09/2016-31/08/2021
New Chelating Agents for Selective Extraction of Uranium (URAEXT)
Tuononen, Heikki
Academy of Finland
01/09/2014-31/08/2018


Ministry reporting: Yes

Reporting Year: 2019

JUFO rating: 1


Last updated on 2020-18-08 at 13:44