A1 Journal article (refereed)
Icosahedral carboranes as scaffolds for congested regioselective polyaryl compounds : the distinct distance tuning of C-C and its antipodal B-B (2019)


Kelemen, Zsolt; Pepiol, Ariadna; Lupu, Marius; Sillanpää, Reijo; Hänninen, Mikko M.; Teixidor, Francesc; Viñas, Clara (2019). Icosahedral carboranes as scaffolds for congested regioselective polyaryl compounds : the distinct distance tuning of C-C and its antipodal B-B. Chemical Communications, 55 (61), 8927-8930. DOI: 10.1039/C9CC04526K


JYU authors or editors


Publication details

All authors or editors: Kelemen, Zsolt; Pepiol, Ariadna; Lupu, Marius; Sillanpää, Reijo; Hänninen, Mikko M.; Teixidor, Francesc; Viñas, Clara

Journal or series: Chemical Communications

ISSN: 1359-7345

eISSN: 1364-548X

Publication year: 2019

Volume: 55

Issue number: 61

Pages range: 8927-8930

Publisher: Royal Society of Chemistry

Publication country: United Kingdom

Publication language: English

DOI: http://doi.org/10.1039/C9CC04526K

Open Access: Open access publication published in a hybrid channel

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/65816


Abstract

Four-fold aryl substituted o-carborane derivatives with defined patterns of substitution at the antipodal region of the cluster carbon atoms have been achieved. It is proven that this region is congested but lacks steric hindrance. Also, the two antipodal sites Cc-Cc and B9-B12 are affected very distinctly by electron donor substituents.


Keywords: chemical compounds; clusters; boron

Free keywords: cluster compounds; carboranes


Contributing organizations


Ministry reporting: Yes

Reporting Year: 2019

JUFO rating: 2


Last updated on 2020-09-07 at 11:55