A1 Journal article (refereed)
Formation and trapping of the thermodynamically unfavoured inverted-hemicucurbit[6]uril (2019)


Prigorchenko, E., Kaabel, S., Narva, T., Baškir, A., Fomitšenko, M., Adamson, J., Järving, I., Rissanen, K., Tamm, T., & Aav, R. (2019). Formation and trapping of the thermodynamically unfavoured inverted-hemicucurbit[6]uril. Chemical Communications, 55(63), 9307-9310. https://doi.org/10.1039/C9CC04990H


JYU authors or editors


Publication details

All authors or editorsPrigorchenko, Elena; Kaabel, Sandra; Narva, Triin; Baškir, Anastassia; Fomitšenko, Maria; Adamson, Jasper; Järving, Ivar; Rissanen, Kari; Tamm, Toomas; Aav, Riina

Journal or seriesChemical Communications

ISSN1359-7345

eISSN1364-548X

Publication year2019

Volume55

Issue number63

Pages range9307-9310

PublisherRoyal Society of Chemistry

Publication countryUnited Kingdom

Publication languageEnglish

DOIhttps://doi.org/10.1039/C9CC04990H

Publication open accessNot open

Publication channel open access

Web address of parallel published publication (pre-print)https://chemrxiv.org/articles/Formation_and_Trapping_of_the_Thermodynamically_Unfavoured_Inverted-Hemicucurbit_6_uril/7977566/1


Abstract

Formation of inverted-cis-cyclohexanohemicucurbit[6]uril (i-cis-cycHC[6]), with up to 33% isolated yield, can be induced at the expense of thermodynamically favoured cis-cycHC[6]. Reaction selectivity is governed by the solution-based template-aided dynamic combinatorial chemistry and continuous precipitation of the formed macrocycles. Different binding affinities of three diastereomeric cycHC[6]s with trifluoroacetic acid is demonstrated.


Keywordssupramolecular chemistry


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Ministry reportingYes

Reporting Year2019

JUFO rating2


Last updated on 2024-11-03 at 14:24