A1 Journal article (refereed)
Formation and trapping of the thermodynamically unfavoured inverted-hemicucurbit[6]uril (2019)
Prigorchenko, E., Kaabel, S., Narva, T., Baškir, A., Fomitšenko, M., Adamson, J., Järving, I., Rissanen, K., Tamm, T., & Aav, R. (2019). Formation and trapping of the thermodynamically unfavoured inverted-hemicucurbit[6]uril. Chemical Communications, 55(63), 9307-9310. https://doi.org/10.1039/C9CC04990H
JYU authors or editors
Publication details
All authors or editors: Prigorchenko, Elena; Kaabel, Sandra; Narva, Triin; Baškir, Anastassia; Fomitšenko, Maria; Adamson, Jasper; Järving, Ivar; Rissanen, Kari; Tamm, Toomas; Aav, Riina
Journal or series: Chemical Communications
ISSN: 1359-7345
eISSN: 1364-548X
Publication year: 2019
Volume: 55
Issue number: 63
Pages range: 9307-9310
Publisher: Royal Society of Chemistry
Publication country: United Kingdom
Publication language: English
DOI: https://doi.org/10.1039/C9CC04990H
Publication open access: Not open
Publication channel open access:
Web address of parallel published publication (pre-print): https://chemrxiv.org/articles/Formation_and_Trapping_of_the_Thermodynamically_Unfavoured_Inverted-Hemicucurbit_6_uril/7977566/1
Abstract
Formation of inverted-cis-cyclohexanohemicucurbit[6]uril (i-cis-cycHC[6]), with up to 33% isolated yield, can be induced at the expense of thermodynamically favoured cis-cycHC[6]. Reaction selectivity is governed by the solution-based template-aided dynamic combinatorial chemistry and continuous precipitation of the formed macrocycles. Different binding affinities of three diastereomeric cycHC[6]s with trifluoroacetic acid is demonstrated.
Keywords: supramolecular chemistry
Contributing organizations
Related projects
- Innovative sensor Devices for the ENanTIoselective detection of CHIral Pollutants
- Rissanen, Kari
- European Commission
Ministry reporting: Yes
Reporting Year: 2019
JUFO rating: 2