A1 Journal article (refereed)
The Role of Nanocrystal Symmetry in the Crossover Region from Molecular to Metallic Gold Nanoparticles (2019)


Malola, S., Kaappa, S., & Häkkinen, H. (2019). The Role of Nanocrystal Symmetry in the Crossover Region from Molecular to Metallic Gold Nanoparticles. Journal of Physical Chemistry C, 123(33), 20655-20663. https://doi.org/10.1021/acs.jpcc.9b05863


JYU authors or editors


Publication details

All authors or editors: Malola, Sami; Kaappa, Sami; Häkkinen, Hannu

Journal or series: Journal of Physical Chemistry C

ISSN: 1932-7447

eISSN: 1932-7455

Publication year: 2019

Volume: 123

Issue number: 33

Pages range: 20655-20663

Publisher: American Chemical Society

Publication country: United States

Publication language: English

DOI: https://doi.org/10.1021/acs.jpcc.9b05863

Publication open access: Not open

Publication channel open access:

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/65418


Abstract

There is a wide-spread interest to design ambient-stable gold nanoparticles with tailored physico-chemical properties for applications in several areas such as plasmonics, nanomedicine, catalysis, biological imaging, sensing, and nanoelectronics. It has been known for a long time that optical response of gold nanoparticles changes drastically in a cross-over region from 150 to 250 gold atoms, from a “molecule-like” to “metallic” behavior, but insufficient knowledge of atomic structures has precluded detailed computational studies on the underlying mechanisms. Here, we analyze the electronic structure and optical and chiroptical properties of recently reported gold nanoparticles of 144, 146, and 246 gold atoms, that are made by wet-chemistry methods and whose structures have been resolved to atomic precision. We demonstrate computationally how re-grouping of the quantum states of valence electrons can affect drastically the optical properties of nanoparticles in the crossover-size region, by either generating a multi-band “molecule-like” or a monotonous “plasmon-like” or “metallic” optical absorption. The lower the symmetry of the gold core, the more “metallic” is the nanoparticle. The underlying mechanism arises from symmetry-sensitive distribution of the electronic levels of the nanoparticle close to Fermi energy.


Keywords: nanoparticles

Free keywords: nanoparticles


Contributing organizations


Related projects


Ministry reporting: Yes

Reporting Year: 2019

JUFO rating: 2


Last updated on 2021-09-06 at 22:17