A1 Journal article (refereed)
Bifunctional coordination polymers as efficient catalysts for carbon dioxide conversion (2019)
Arunachalam, Rajendran; Chinnaraja, Eswaran; Valkonen, Arto; Rissanen, Kari; Subramanian, Palani S. (2019). Bifunctional coordination polymers as efficient catalysts for carbon dioxide conversion. Applied Organometallic Chemistry, 33 (11), e5202. DOI: 10.1002/aoc.5202
JYU authors or editors
Publication details
All authors or editors: Arunachalam, Rajendran; Chinnaraja, Eswaran; Valkonen, Arto; Rissanen, Kari; Subramanian, Palani S.
Journal or series: Applied Organometallic Chemistry
ISSN: 0268-2605
eISSN: 1099-0739
Publication year: 2019
Volume: 33
Issue number: 11
Article number: e5202
Publisher: John Wiley & Sons
Publication country: United Kingdom
Publication language: English
DOI: https://doi.org/10.1002/aoc.5202
Open Access: Publication channel is not openly available
Abstract
The multidentate ligand H2L upon complexation with Zn (II) and Cd (II) provide a one‐dimensional polymeric networks. These coordination polymers (CPs) CP‐1 and CP‐2 containing Zn (II) and Cd (II) metals respectively are well characterized. The single crystal structural analysis confirms the formation of one‐dimensional coordination polymer with zigzag fashion in CP‐1 and ladder chain CP‐2. Both the CPs are applied as catalysts to synthesize various cyclic carbonates from epoxides and carbon dioxide. The catalysts are giving better conversion under solvent‐free and additive‐free condition using 10 bar CO2 and 100 °C as optimized pressure and temperature. The detailed kinetic experiments suggesting the first order kinetics, the energy of activation (Ea) is calculated for this catalytic conversion.
Keywords: polymers; chemical reactions; carbon dioxide
Free keywords: activation energy; CO2utilization; coordination polymers; cyclic carbonates; reaction kinetics
Contributing organizations
Related projects
- Robust S...I+...S Halogen Bonded Supramolecular Assemblies (research costs)
- Valkonen, Arto
- Academy of Finland
Ministry reporting: Yes
Reporting Year: 2019
JUFO rating: 1