A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
Mononuclear Ru(II) PolyPyridyl Water Oxidation Catalysts Decorated with Perfluoroalkyl C8H17‐Tag Bearing Chains (2019)
Tatikonda, R., Cametti, M., Kalenius, E., Famulari, A., Rissanen, K., & Haukka, M. (2019). Mononuclear Ru(II) PolyPyridyl Water Oxidation Catalysts Decorated with Perfluoroalkyl C8H17‐Tag Bearing Chains. European Journal of Inorganic Chemistry, (10), 4463-4470. https://doi.org/10.1002/ejic.201900579
JYU-tekijät tai -toimittajat
Julkaisun tiedot
Julkaisun kaikki tekijät tai toimittajat: Tatikonda, Rajendhraprasad; Cametti, Massimo; Kalenius, Elina; Famulari, Antonino; Rissanen, Kari; Haukka, Matti
Lehti tai sarja: European Journal of Inorganic Chemistry
ISSN: 1434-1948
eISSN: 1099-0682
Julkaisuvuosi: 2019
Lehden numero: 10
Artikkelin sivunumerot: 4463-4470
Kustantaja: Wiley-VCH Verlag
Julkaisumaa: Saksa
Julkaisun kieli: englanti
DOI: https://doi.org/10.1002/ejic.201900579
Julkaisun avoin saatavuus: Ei avoin
Julkaisukanavan avoin saatavuus:
Tiivistelmä
A set of novel polypyridyl Ru(II) complexes 1–7, decorated with one, two or three C8F17 tags have been synthesized and characterized by NMR, UV/Vis spectroscopy and, in the case of series of complexes 1–3, 5 and 7 by X‐ray diffraction on single crystals. Solid state structures of 3, 5 and 7 were also subjected to computational DFT study in order to gain insights into the effect of a different number of perfluorinated tags on their stability in the solid‐state. The complexes are stable in solution under strongly oxidative conditions, do keep catalytic activity in their aquo forms (1′‐7′) comparing well with parent complex 8′, and their amphiphilic nature could allow for their incorporation in fluorous media and interfaces.
YSO-asiasanat: kompleksiyhdisteet; katalyytit; hapetus-pelkistysreaktio; tiheysfunktionaaliteoria
Vapaat asiasanat: x-ray structures; density functional; calculations; water oxidation; fluorous phases; Ru(II)polypyridyl complexes
Liittyvät organisaatiot
OKM-raportointi: Kyllä
Raportointivuosi: 2019
JUFO-taso: 1
