A1 Journal article (refereed)
Cocrystal trimorphism as a consequence of the orthogonality of halogen- and hydrogen-bonds synthons (2019)


Topić, Filip; Lisac, Katarina; Arhangelskis, Mihails; Rissanen, Kari; Cinčić, Dominik; Friščić, Tomislav (2019). Cocrystal trimorphism as a consequence of the orthogonality of halogen- and hydrogen-bonds synthons. Chemical Communications, 55 (93), 14066-14069. DOI: 10.1039/C9CC06735C


JYU authors or editors


Publication details

All authors or editors: Topić, Filip; Lisac, Katarina; Arhangelskis, Mihails; Rissanen, Kari; Cinčić, Dominik; Friščić, Tomislav

Journal or series: Chemical Communications

ISSN: 1359-7345

eISSN: 1364-548X

Publication year: 2019

Volume: 55

Issue number: 93

Pages range: 14066-14069

Publisher: Royal Society of Chemistry

Publication country: United Kingdom

Publication language: English

DOI: https://doi.org/10.1039/C9CC06735C

Open Access: Publication channel is not openly available

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/67393


Abstract

True trimorphic cocrystals, i.e. multi-component molecular crystals of identical composition that exhibit three polymorphic structures, are exceedingly rare and so far no halogen-bonded cocrystal system has been reported to exhibit trimorphism. Here we describe a unique example of a trimorphic cocrystal exhibiting both hydrogen and halogen bonds in which the differences between polymorphs reveal their orthogonality, evident by the apparently independent variation of well-defined hydrogen- and halogen-bonded motifs.


Keywords: supramolecular chemistry; crystals; chemical bonds; hydrogen bonds


Contributing organizations


Ministry reporting: Yes

Reporting Year: 2019

JUFO rating: 2


Last updated on 2020-18-08 at 13:21