A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
Novel Functionality of Lithium-Impregnated Titania as Nanocatalyst (2019)
Ambat, I., Srivastava, V., Haapaniemi, E., & Sillanpää, M. (2019). Novel Functionality of Lithium-Impregnated Titania as Nanocatalyst. Catalysts, 9(11), Article 943. https://doi.org/10.3390/catal9110943
JYU-tekijät tai -toimittajat
Julkaisun tiedot
Julkaisun kaikki tekijät tai toimittajat: Ambat, Indu; Srivastava, Varsha; Haapaniemi, Esa; Sillanpää, Mika
Lehti tai sarja: Catalysts
eISSN: 2073-4344
Julkaisuvuosi: 2019
Volyymi: 9
Lehden numero: 11
Artikkelinumero: 943
Kustantaja: MDPI AG
Julkaisumaa: Sveitsi
Julkaisun kieli: englanti
DOI: https://doi.org/10.3390/catal9110943
Julkaisun avoin saatavuus: Avoimesti saatavilla
Julkaisukanavan avoin saatavuus: Kokonaan avoin julkaisukanava
Julkaisu on rinnakkaistallennettu (JYX): https://jyx.jyu.fi/handle/123456789/66444
Tiivistelmä
The present work incorporates the synthesis of a multifunctional catalyst for the transesterification of waste cooking oil (WCO) to biodiesel and recovery of rare earth elements (REEs). For this purpose, TiO2 nanoparticles and TiO2 doped with lithium ions were prepared. The influence of lithium ions on the catalytic performance of TiO2 was attained by impregnation of the different molar ratios of lithium hydroxide to bare TiO2. Then each catalyst was screened for catalytic conversion of WCO to fatty acid methyl ester (FAME) and also for REEs recovery. All synthesized materials were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), Transmission electron microscopy (TEM), Brunauer–Emmett–Teller (BET) analysis, and Hammett indicator for the basicity test. The obtained biodiesel was characterized by gas chromatography with mass spectrometry (GC-MS), 1H, and 13C nuclear magnetic resonance (NMR). Moreover, the physical parameters of the synthesized biodiesel were also determined. The REEs recovery efficiency of synthesized nanomaterials was investigated, and the percentage of REEs removal was determined by inductively-coupled plasma optical emission spectroscopy (ICP-OES).
YSO-asiasanat: katalyytit; nanohiukkaset; titaanidioksidi; litium; biodiesel; kasviöljyt; harvinaiset maametallit
Vapaat asiasanat: biodiesel; rare earth elements; TiO2; nanocatalyst; waste cooking oil
Liittyvät organisaatiot
OKM-raportointi: Kyllä
Raportointivuosi: 2019
JUFO-taso: 1