A1 Journal article (refereed)
Bioinspired Mo, W and V complexes bearing a highly hydroxyl-functionalized Schiff base ligand (2020)
Salonen, P., & Lehtonen, A. (2020). Bioinspired Mo, W and V complexes bearing a highly hydroxyl-functionalized Schiff base ligand. Inorganica Chimica Acta, 503, Article 119414. https://doi.org/10.1016/j.ica.2020.119414
JYU authors or editors
Publication details
All authors or editors: Salonen, Pasi, Peuronen, Anssi; Lehtonen, Ari
Journal or series: Inorganica Chimica Acta
ISSN: 0020-1693
eISSN: 1873-3255
Publication year: 2020
Volume: 503
Article number: 119414
Publisher: Elsevier BV
Publication country: Netherlands
Publication language: English
DOI: https://doi.org/10.1016/j.ica.2020.119414
Publication open access: Not open
Publication channel open access:
Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/68718
Abstract
A series of bioinspired dioxidomolybdenum(vi), dioxidotungsten(vi) and oxidovanadium(v) complexes [MoO2(H2LSaltris)], [WO2(H2LSaltris)] and [VO(HLSaltris)]2 were prepared by the reaction of a hydroxyl-rich Schiff base proligand N-(1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl)-3,5-di-tert-butylsalicylaldimine (H4LSaltris) with metal precursors in methanol solutions. Molybdenum and tungsten complexes crystallize as mononuclear molecules, whereas the vanadium complex forms dinuclear units. From the complexes, [VO(HLSaltris)]2 shows activity in the oxidation of 4-tert-butylcatechol and 3,5-di-tert-butylcatechol, mimicking the action of the dicopper enzyme catechol oxidase.
Keywords: inorganic chemistry
Free keywords: inorganic chemistry
Contributing organizations
Ministry reporting: Yes
Reporting Year: 2020
JUFO rating: 1