A1 Journal article (refereed)
Synthesis and Structure of Trimethylplatinum(IV) Iodide Complex of 4'‐(4‐Methoxyphenyl)‐2,2':6',2''‐terpyridine Ligand and its Halogen Bonding Property (2020)
Das, D., Sutradhar, S., Rissanen, K., & Ghosh, B. N. (2020). Synthesis and Structure of Trimethylplatinum(IV) Iodide Complex of 4'‐(4‐Methoxyphenyl)‐2,2':6',2''‐terpyridine Ligand and its Halogen Bonding Property. Zeitschrift fur anorganische und allgemeine Chemie, 646(5), 301-306. https://doi.org/10.1002/zaac.201900201
JYU authors or editors
Publication details
All authors or editors: Das, Dipankar; Sutradhar, Sourav; Rissanen, Kari; Ghosh, Biswa Nath
Journal or series: Zeitschrift fur anorganische und allgemeine Chemie
ISSN: 0044-2313
eISSN: 1521-3749
Publication year: 2020
Volume: 646
Issue number: 5
Pages range: 301-306
Publisher: Wiley-VCH Verlag
Publication country: Germany
Publication language: English
DOI: https://doi.org/10.1002/zaac.201900201
Publication open access: Not open
Publication channel open access:
Abstract
The synthesis and structural characterization of a new trimethylplatinum(IV) iodide complex of 4'‐(4‐methoxyphenyl)‐2,2':6',2''‐terpyridine ligand L, {PtMe3IL} (1) is reported. The X‐ray crystal structure shows that the terpyridine ligand L binds the platinum(IV) metal center in bidentate fashion, which is well supported by the 1H NMR spectrum of 1. The complex 1 upon crystallization with 1,4‐diiodotetrafluorobenzene (DITFB) forms the halogen bonded complex 1a (1·DITFB). The structural investigation shows that 1a exhibits the halogen bonding interaction in which the non‐coordinated pyridyl nitrogen acts as halogen bond acceptors by forming I···N interaction with iodine atom of DITFB. In addition iodine atom of complex 1 also acts as weak halogen bond acceptor.
Keywords: halogens
Free keywords: halogen bond; Trimethylplatinum(IV); Terpyridine; 1,4‐Diiodotetrafluorobenzene (DITFB); X‐ray diffraction
Contributing organizations
Ministry reporting: Yes
Reporting Year: 2020
JUFO rating: 1
