A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
The Effect of Mechanocatalytic Pretreatment on the Structure and Depolymerization of Willow (2020)
Lempiäinen, H., Lappalainen, K., Haverinen, J., Tuuttila, T., Hu, T., Jaakkola, M., & Lassi, U. (2020). The Effect of Mechanocatalytic Pretreatment on the Structure and Depolymerization of Willow. Catalysts, 10(2), Article 255. https://doi.org/10.3390/catal10020255
JYU-tekijät tai -toimittajat
Julkaisun tiedot
Julkaisun kaikki tekijät tai toimittajat: Lempiäinen, Henna; Lappalainen, Katja; Haverinen, Jasmiina; Tuuttila, Tero; Hu, Tao; Jaakkola, Mari; Lassi, Ulla
Lehti tai sarja: Catalysts
eISSN: 2073-4344
Julkaisuvuosi: 2020
Volyymi: 10
Lehden numero: 2
Artikkelinumero: 255
Kustantaja: MDPI
Julkaisumaa: Sveitsi
Julkaisun kieli: englanti
DOI: https://doi.org/10.3390/catal10020255
Julkaisun avoin saatavuus: Avoimesti saatavilla
Julkaisukanavan avoin saatavuus: Kokonaan avoin julkaisukanava
Julkaisu on rinnakkaistallennettu (JYX): https://jyx.jyu.fi/handle/123456789/67986
Lisätietoja: This article belongs to the Special Issue Direct Catalytic Conversion of Raw or Waste Biomass to Biofuels and Chemical Building Blocks.
Tiivistelmä
In this study, the effect of a mechanocatalytic pretreatment on the structure of willow and sugar release from pretreated willow was explored. In the mechanocatalytic approach, the pretreatment consists of solvent-free impregnation with sulfuric acid and a mechanical treatment with ball milling. Willow sawdust and pretreated samples were analyzed with field emission scanning electron microscope and X-ray diffraction. The products in the sugar solution were determined as the total reducing sugars with the 3,5-dinitrosalicylic acid method and monosaccharides with capillary electrophoresis. According to the results, milling increased the sugar production, depending on the sulfuric acid load. The milling parameters, such as the rotation speed of the mill, the catalyst-to-willow ratio, and the milling time influenced the amount of sugars in the hydrolysate and the composition of the sugar solution produced. Changes were observed in the surface of the willow particles as well as changes in the crystalline structure. Glucose and xylose yields increased after 15 min of milling and reached their maximum level after 45 min of milling with the 0.5 mmol/g sulfuric acid load.
YSO-asiasanat: selluloosa; esikäsittely; rikkihappo; pajut; polymerointi
Vapaat asiasanat: willow sawdust; lignocellulose; sulfuric acid; mechanocatalytic pretreatment; ball milling
Liittyvät organisaatiot
Hankkeet, joissa julkaisu on tehty
- Biojalostuksen arvoketjut
- Lempiäinen, Henna
- Keski-Pohjanmaan liitto
- Bioraff Botnia
- Asplund, Tina
- Euroopan komissio
OKM-raportointi: Kyllä
Raportointivuosi: 2020
JUFO-taso: 1