A1 Journal article (refereed)
Supramolecular Assembly of Metal Complexes by (Aryl)I⋯dz2[PtII] Halogen Bond (2020)

Katlenok, E. A., Haukka, M., Levin, O. V., Frontera, A., & Kukushkin, V. Y. (2020). Supramolecular Assembly of Metal Complexes by (Aryl)I⋯dz2[PtII] Halogen Bond. Chemistry : A European Journal, 26(34), 7692-7701. https://doi.org/10.1002/chem.202001196

JYU authors or editors

Publication details

All authors or editors: Katlenok, Eugenе A.; Haukka, Matti; Levin, Oleg V.; Frontera, Antonio; Kukushkin, Vadim Yurievich

Journal or series: Chemistry : A European Journal

ISSN: 0947-6539

eISSN: 1521-3765

Publication year: 2020

Volume: 26

Issue number: 34

Pages range: 7692-7701

Publisher: Wiley-VCH Verlag

Publication country: Germany

Publication language: English

DOI: https://doi.org/10.1002/chem.202001196

Publication open access: Not open

Publication channel open access:

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/68482

Abstract

The theoretical data for the half‐lantern complexes [Pt(C^N)(μ‐S^N)] 2 ( 1 – 3 ; С^N is cyclometalated 2‐Ph‐benzothiazole; S^N is 2‐SH‐pyridine 1 , 2‐SH‐benzoxazole 2 , 2‐SH‐tetrafluorobenzothiazole 3 ) indicate that the Pt···Pt orbital interaction leads to an increment of the nucleophilicity of the outer d z 2 ‐orbitals to provide assembly with electrophilic species. 1 – 3 were co‐crystallized with bifunctional halogen bond (XB) donors to give adducts ( 1 – 3 ) 2 ∙(1,4‐diiodotetrafluorobenzene) and infinite polymeric [ 1 ·1,1’‐diiodoperfluorodiphenyl] n . X‐ray crystallography revealed that the supramolecular assembly is achieved via (Aryl)I∙∙∙ d z 2 [Pt II ] XB between iodine σ‐holes and lone pairs of the positively charged (Pt II ) 2 centers, acting as nucleophilic sites. The polymer includes a curved linear chain ···Pt 2 ···I(arene F )I···Pt 2 ··· involving XB between iodines of the perfluoroarene linkers and (Pt II ) 2 moieties. The 195 Pt NMR, UV‐vis, and CV studies indicate that XB is preserved in CH(D) 2 Cl 2 solutions.

Keywords: supramolecular chemistry; chemical bonds; coordination complexes; platinum

Free keywords: halogen bonding; supramolecular chemistry; cyclometalated complex; platinum; theoretical calculations

Contributing organizations

Ministry reporting: Yes

Reporting Year: 2020

JUFO rating: 2