A1 Journal article (refereed)
Asymmetric [N–I–N]+ halonium complexes (2020)


Ward, Jas S.; Fiorini, Giorgia; Frontera, Antonio; Rissanen, Kari (2020). Asymmetric [N–I–N]+ halonium complexes. Chemical Communications, 56 (60), 8428-8431. DOI: 10.1039/d0cc02758h


JYU authors or editors


Publication details

All authors or editors: Ward, Jas S.; Fiorini, Giorgia; Frontera, Antonio; Rissanen, Kari

Journal or series: Chemical Communications

ISSN: 1359-7345

eISSN: 1364-548X

Publication year: 2020

Volume: 56

Issue number: 60

Pages range: 8428-8431

Publisher: Royal Society of Chemistry

Publication country: United Kingdom

Publication language: English

DOI: https://doi.org/10.1039/d0cc02758h

Open Access: Open access publication published in a hybrid channel

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/71068


Abstract

The first asymmetric halogen-bonded iodonium complexes [I(py)(4-DMAP)]PF6 (2c) and [I(py)(4-Etpy)]PF6 (2e) were prepared via [N-Ag-N]+ → [N-I-N]+ cation exchange of their analogous 2-coordinate silver complexes. The complexes were characterised by 1H and 1H-15N HMBC NMR spectroscopy, and single crystal X-ray crystallography.


Keywords: coordination complexes; halogens; chemical bonds


Contributing organizations


Ministry reporting: Yes


Last updated on 2020-18-08 at 13:30