A1 Journal article (refereed)
Helicates with Ether‐Substituted Catechol Esters as Ligands (2020)


Mevissen, Christian; Kwamen, Carel; Himmel, Leonard; Chen, Xiaofei; Brückner, Matthias; Huda, Saskia; Göb, Christian; Jenniches, Judith; Oppel, Iris; Ward, James; Rissanen, Kari; Albrecht, Markus (2020). Helicates with Ether‐Substituted Catechol Esters as Ligands. European Journal of Organic Chemistry, 2020 (32), 5161-5172. DOI: 10.1002/ejoc.202000843


JYU authors or editors


Publication details

All authors or editors: Mevissen, Christian; Kwamen, Carel; Himmel, Leonard; Chen, Xiaofei; Brückner, Matthias; Huda, Saskia; Göb, Christian; Jenniches, Judith; Oppel, Iris; Ward, James; et al.

Journal or series: European Journal of Organic Chemistry

ISSN: 1434-193X

eISSN: 1099-0690

Publication year: 2020

Volume: 2020

Issue number: 32

Pages range: 5161-5172

Publisher: Wiley

Publication country: Germany

Publication language: English

DOI: http://doi.org/10.1002/ejoc.202000843

Open Access: Open access publication published in a hybrid channel

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/71826


Abstract

Mono‐ or biscatechol esters with ether‐type substituents or spacers form either triple lithium bridged dimeric helicates or triple stranded helicates with the ability to bind three lithium cations in their interior. Hierarchical helicates with ether or thioether substituents show in solution a monomer‐dimer equilibrium which is independent of the heteroatom in the ester substituent. However, dimerization constants are significantly lower than for corresponding alkyl derivatives. Dinuclear helicates with oligoether spacers are well obtained in the presence of lithium cations. Upon removal of the cations the helicates expand and successive addition of LiCl results in compression again.


Keywords: supramolecular chemistry; coordination complexes; lithium; esters; thermodynamics

Free keywords: helicate; templating; molecular switch; thermodynamics; catecholate


Contributing organizations


Ministry reporting: Yes

Preliminary JUFO rating: 1


Last updated on 2020-21-09 at 17:09