A1 Journal article (refereed)
Helicates with Ether‐Substituted Catechol Esters as Ligands (2020)


Mevissen, C., Kwamen, C., Himmel, L., Chen, X., Brückner, M., Huda, S., Göb, C., Jenniches, J., Oppel, I., Ward, J., Rissanen, K., & Albrecht, M. (2020). Helicates with Ether‐Substituted Catechol Esters as Ligands. European Journal of Organic Chemistry, 2020(32), 5161-5172. https://doi.org/10.1002/ejoc.202000843


JYU authors or editors


Publication details

All authors or editorsMevissen, Christian; Kwamen, Carel; Himmel, Leonard; Chen, Xiaofei; Brückner, Matthias; Huda, Saskia; Göb, Christian; Jenniches, Judith; Oppel, Iris; Ward, James; et al.

Journal or seriesEuropean Journal of Organic Chemistry

ISSN1434-193X

eISSN1099-0690

Publication year2020

Publication date11/07/2020

Volume2020

Issue number32

Pages range5161-5172

PublisherWiley

Publication countryGermany

Publication languageEnglish

DOIhttps://doi.org/10.1002/ejoc.202000843

Publication open accessOpenly available

Publication channel open accessPartially open access channel

Publication is parallel published (JYX)https://jyx.jyu.fi/handle/123456789/71826


Abstract

Mono‐ or biscatechol esters with ether‐type substituents or spacers form either triple lithium bridged dimeric helicates or triple stranded helicates with the ability to bind three lithium cations in their interior. Hierarchical helicates with ether or thioether substituents show in solution a monomer‐dimer equilibrium which is independent of the heteroatom in the ester substituent. However, dimerization constants are significantly lower than for corresponding alkyl derivatives. Dinuclear helicates with oligoether spacers are well obtained in the presence of lithium cations. Upon removal of the cations the helicates expand and successive addition of LiCl results in compression again.


Keywordssupramolecular chemistrycoordination complexeslithiumestersthermodynamics

Free keywordshelicate; templating; molecular switch; thermodynamics; catecholate


Contributing organizations


Ministry reportingYes

Reporting Year2020

JUFO rating1


Last updated on 2024-22-04 at 13:44