A2 Katsausartikkeli tieteellisessä aikausilehdessä
Advances and challenges for experiment and theory for multi-electron multi-proton transfer at electrified solid–liquid interfaces (2020)

Sakaushi, K., Kumeda, T., Hammes-Schiffer, S., Melander, M. M., & Sugino, O. (2020). Advances and challenges for experiment and theory for multi-electron multi-proton transfer at electrified solid–liquid interfaces. Physical Chemistry Chemical Physics, 22(35), 19401-19442. https://doi.org/10.1039/D0CP02741C

JYU-tekijät tai -toimittajat

Melander, Marko

Julkaisun tiedot

Julkaisun kaikki tekijät tai toimittajat: Sakaushi, Ken; Kumeda, Tomoaki; Hammes-Schiffer, Sharon; Melander, Marko M.; Sugino, Osamu

Lehti tai sarja: Physical Chemistry Chemical Physics

ISSN: 1463-9076

eISSN: 1463-9084

Julkaisuvuosi: 2020

Volyymi: 22

Lehden numero: 35

Artikkelin sivunumerot: 19401-19442

Kustantaja: Royal Society of Chemistry (RSC)

Julkaisumaa: Britannia

Julkaisun kieli: englanti

DOI: https://doi.org/10.1039/D0CP02741C

Julkaisun avoin saatavuus: Avoimesti saatavilla

Julkaisukanavan avoin saatavuus: Osittain avoin julkaisukanava

Julkaisu on rinnakkaistallennettu (JYX): https://jyx.jyu.fi/handle/123456789/71642

Tiivistelmä

Multi-electron, multi-proton transfer is important in a wide spectrum of processes spanning biological, chemical and physical systems. These reactions have attracted significant interest due to both fundamental curiosity and potential applications in energy technology. In this Perspective Review, we shed light on modern aspects of electrode processes in the 21st century, in particular on the recent advances and challenges in multistep electron/proton transfers at solid–liquid interfaces. Ongoing developments of analytical techniques and operando spectrometry at electrode/electrolyte interfaces and reliable computational approaches to simulate complicated interfacial electrochemical reactions enable us to obtain microscopic insights about these complex processes, such as the role of quantum effects in electrochemical reactions. Our motivation in this Perspective Review is to provide a comprehensive survey and discussion of state-of-the-art developments in experiments, materials, and theories for modern electrode process science, as well as to present an outlook for the future directions in this field.

YSO-asiasanat: sähkökemia; pintakemia; elektrodit

Vapaat asiasanat: multi-electron multi-proton transfer; electrified solid–liquid interfaces

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