A1 Journal article (refereed)
A Bis‐Acridinium Macrocycle as Multi‐Responsive Receptor and Selective Phase‐Transfer Agent of Perylene (2020)


Hu, Johnny; Ward, Jas S.; Chaumont, Alain; Rissanen, Kari; Vincent, Jean-Marc; Heitz, Valérie; Jacquot de Rouville, Henri-Pierre (2020). A Bis‐Acridinium Macrocycle as Multi‐Responsive Receptor and Selective Phase‐Transfer Agent of Perylene. Angewandte Chemie, Early online. DOI: 10.1002/anie.202009212


JYU authors or editors


Publication details

All authors or editors: Hu, Johnny; Ward, Jas S.; Chaumont, Alain; Rissanen, Kari; Vincent, Jean-Marc; Heitz, Valérie; Jacquot de Rouville, Henri-Pierre

Journal or series: Angewandte Chemie

ISSN: 1433-7851

eISSN: 1521-3773

Publication year: 2020

Volume: Early online

Publisher: Wiley-VCH Verlag

Publication country: Germany

Publication language: English

DOI: http://doi.org/10.1002/anie.202009212

Open Access: Publication channel is not openly available

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/71652


Abstract

A bis‐acridinium cyclophane incorporating switchable acridinium moieties linked by a 3,5‐dipyridylanisole spacer was studied as a multi‐responsive host for polycyclic aromatic hydrocarbon guests. Complexation of perylene was proven to be the most effective and was characterized in particular by a charge transfer band as signal output. Effective catch and release of the guest was triggered by both chemical (proton/hydroxide) and redox stimuli. Moreover, the dicationic host was also easily switched between organic and perfluorocarbon phases for application related to the enrichment of perylene from a mixture of polycyclic aromatic hydrocarbons.


Keywords: PFC compounds; supramolecular chemistry

Free keywords: multi-responsive receptor; phase transfer; acridinium; perfluorocarbons; host-guest chemistry


Contributing organizations


Ministry reporting: No, publication in press

Preliminary JUFO rating: 3


Last updated on 2020-28-10 at 08:51