A1 Journal article (refereed)
Luminescent PhotoCORMs : Enabling/Disabling CO Delivery upon Blue Light Irradiation (2020)


Weiss, Vitor C.; Farias, Giliandro; Amorim, André L.; Xavier, Fernando R.; Camargo, Tiago P.; Bregalda, Mayana B.; Haukka, Matti; Nordlander, Ebbe; de Souza, Bernardo; Peralta, Rosely A. (2020). Luminescent PhotoCORMs : Enabling/Disabling CO Delivery upon Blue Light Irradiation. Inorganic Chemistry, 59 (18), 13078-13090. DOI: 10.1021/acs.inorgchem.0c00638


JYU authors or editors


Publication details

All authors or editors: Weiss, Vitor C.; Farias, Giliandro; Amorim, André L.; Xavier, Fernando R.; Camargo, Tiago P.; Bregalda, Mayana B.; Haukka, Matti; Nordlander, Ebbe; de Souza, Bernardo; Peralta, Rosely A.

Journal or series: Inorganic Chemistry

ISSN: 0020-1669

eISSN: 1520-510X

Publication year: 2020

Volume: 59

Issue number: 18

Pages range: 13078-13090

Publisher: American Chemical Society (ACS)

Publication country: United States

Publication language: English

DOI: https://doi.org/10.1021/acs.inorgchem.0c00638

Open Access: Publication channel is not openly available


Abstract

The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.


Keywords: photochemistry; luminescence; coordination complexes; ligands; carbon monoxide


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Ministry reporting: Yes

Preliminary JUFO rating: 2


Last updated on 2020-22-09 at 11:18