A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
Organic PolyRadicals as Redox Mediators : Effect of Intramolecular Radical Interactions in their Efficiency (2020)

Badetti, Elena, Lloveras, Vega, Amadio, Emanuele, Di Lorenzo, Rosalia, Olivares-Marin, Mara, Tesio Alvaro Yamil, Zhang, Songbai, Pan, FangFang, Rissanen, Kari, Veciana, Jaume, Tonti, Dino, Vidal-Gancedo, José, Zonta, Cristiano, Licini, Giulia. (2020). Organic PolyRadicals as Redox Mediators : Effect of Intramolecular Radical Interactions in their Efficiency. ACS Applied Materials and Interfaces, 12(41), 45968-45975. https://doi.org/10.1021/acsami.0c09386

JYU-tekijät tai -toimittajat

Pan, Fangfang
Rissanen, Kari

Julkaisun tiedot

Julkaisun kaikki tekijät tai toimittajat: Badetti, Elena; Lloveras, Vega; Amadio, Emanuele; Di Lorenzo, Rosalia; Olivares-Marin, Mara; Tesio Alvaro Yamil; Zhang, Songbai; Pan, FangFang; Rissanen, Kari; Veciana, Jaume; et al.

Lehti tai sarja: ACS Applied Materials and Interfaces

ISSN: 1944-8244

eISSN: 1944-8252

Julkaisuvuosi: 2020

Ilmestymispäivä: 15.09.2020

Volyymi: 12

Lehden numero: 41

Artikkelin sivunumerot: 45968-45975

Kustantaja: American Chemical Society (ACS)

Julkaisumaa: Yhdysvallat (USA)

Julkaisun kieli: englanti

DOI: https://doi.org/10.1021/acsami.0c09386

Julkaisun avoin saatavuus: Avoimesti saatavilla

Julkaisukanavan avoin saatavuus: Osittain avoin julkaisukanava

Julkaisu on rinnakkaistallennettu (JYX): https://jyx.jyu.fi/handle/123456789/71825

Tiivistelmä

The spin-spin interactions between unpaired electrons in organic (poly)radicals, especially nitroxides, are of largely investigated and are of crucial importance for their applications in areas such as organic magnetism, molecular charge transfer or multiple spin labeling in structural biology. Recently, TEMPO and polymers functionalized with nitroxides have been described as successful redox mediators, however, the study of spin-spin interactions effect in such an area is absent. This communication deals with the preparation and study of a novel family of discrete polynitroxide molecules, with the same number of radical units but different arrangement to study how intramolecular spin-spin interactions affect on their electrochemical potential and their use as redox mediators.

YSO-asiasanat: orgaaninen kemia; polymeerikemia; polymeerit; sähkökemia

Vapaat asiasanat: spin-spin interactions

Liittyvät organisaatiot

OKM-raportointi: Kyllä

Raportointivuosi: 2020

JUFO-taso: 2