A1 Journal article (refereed)
Conversion of furfural to 2-methylfuran over CuNi catalysts supported on biobased carbon foams (2021)


Varila, T., Mäkelä, E., Kupila, R., Romar, H., Hu, T., Karinen, R., Puurunen, R. L., & Lassi, U. (2021). Conversion of furfural to 2-methylfuran over CuNi catalysts supported on biobased carbon foams. Catalysis Today, 367, 16-27. https://doi.org/10.1016/j.cattod.2020.10.027


JYU authors or editors


Publication details

All authors or editorsVarila, Toni; Mäkelä, Eveliina; Kupila, Riikka; Romar, Henrik; Hu, Tao; Karinen, Reetta; Puurunen, Riikka L.; Lassi, Ulla

Journal or seriesCatalysis Today

ISSN0920-5861

eISSN1873-4308

Publication year2021

Volume367

Pages range16-27

PublisherElsevier

Publication countryNetherlands

Publication languageEnglish

DOIhttps://doi.org/10.1016/j.cattod.2020.10.027

Publication open accessOther way freely accessible online

Publication channel open access

Publication is parallel published (JYX)https://jyx.jyu.fi/handle/123456789/75035


Abstract

In this study, carbon foams prepared from the by-products of the Finnish forest industry, such as tannic acid and pine bark extracts, were examined as supports for 5/5% Cu/Ni catalysts in the hydrotreatment of furfural to 2-methylfuran (MF). Experiments were conducted in a batch reactor at 503 K and 40 bar H2. Prior to metal impregnation, the carbon foam from tannic acid was activated with steam (S1), and the carbon foam from pine bark extracts was activated with ZnCl2 (S2) and washed with acids (HNO3 or H2SO4). For comparison, a spruce-based activated carbon (AC) catalyst and two commercial AC catalysts as references were investigated. Compressive strength of the foam S2 was 30 times greater than that of S1. The highest MF selectivity of the foam-supported catalysts was 48 % (S2, washed with HNO3) at a conversion of 91 %. According to the results, carbon foams prepared from pine bark extracts can be applied as catalyst supports.


Keywordscatalysiscatalystscoppernickelfoamsbiocharby-products

Free keywordsbiobased foams; carbon; mechanical strength; furfural; Cu/Ni catalyst; 2-methylfuran


Contributing organizations


Related projects


Ministry reportingYes

Reporting Year2021

JUFO rating1


Last updated on 2024-22-04 at 22:15