A1 Journal article (refereed)
Asymmetric [N–I–N]+ halonium complexes in solution? (2020)


von der Heiden, D., Rissanen, K., & Erdélyi, M. (2020). Asymmetric [N–I–N]+ halonium complexes in solution?. Chemical Communications, 56(92), 14431-14434. https://doi.org/10.1039/D0CC06706G


JYU authors or editors


Publication details

All authors or editors: von der Heiden, Daniel; Rissanen, Kari; Erdélyi, Máté

Journal or series: Chemical Communications

ISSN: 1359-7345

eISSN: 1364-548X

Publication year: 2020

Volume: 56

Issue number: 92

Pages range: 14431-14434

Publisher: American Chemical Society

Publication country: United States

Publication language: English

DOI: https://doi.org/10.1039/D0CC06706G

Publication open access: Openly available

Publication channel open access: Partially open access channel

Publication is parallel published (JYX): https://jyx.jyu.fi/handle/123456789/72833


Abstract

Assessment of the solution equilibria of [bis(pyridine)iodine(I)]+ complexes by ESI-MS and NMR reveals the preference of iodine(I) to form complexes with a more basic pyridine. Mixtures of symmetric [bis(pyridine)iodine(I)]+ complexes undergo statistical ligand exchange, with a predominant entropic driving force favoring asymmetric systems. The influence of ligand basicity, concentration, temperature, and ligand composition is evaluated. Our findings are expected to facilitate the investigations, and the supramolecular and synthetic applications of halonium ions’ halogen bonds.


Keywords: coordination complexes; iodine; ligands; solutions (liquids)


Contributing organizations


Ministry reporting: Yes

Reporting Year: 2020

JUFO rating: 2


Last updated on 2021-07-07 at 21:35