A2 Review article, Literature review, Systematic review
Recent Advances in Halogen Bonded Assemblies with Resorcin[4]arenes (2021)


Twum, Kwaku; Rissanen, Kari; Beyeh, Ngong Kodiah (2021). Recent Advances in Halogen Bonded Assemblies with Resorcin[4]arenes. Chemical Record, 21 (2), 386-395. DOI: 10.1002/tcr.202000140


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Publication details

All authors or editors: Twum, Kwaku; Rissanen, Kari; Beyeh, Ngong Kodiah

Journal or series: Chemical Record

ISSN: 1527-8999

eISSN: 1528-0691

Publication year: 2021

Volume: 21

Issue number: 2

Pages range: 386-395

Publisher: Wiley-VCH Verlag

Publication country: Germany

Publication language: English

DOI: https://doi.org/10.1002/tcr.202000140

Open Access: Publication channel is not openly available

Additional information: 4th International Symposium on Halogen Bonding.


Abstract

Resorcinarenes are cavity‐containing compounds when in the crown conformation, from the calixarene family of concave compounds. These easy to synthesize macrocycles can be decorated at the upper rim through the eight hydroxyl groups and/or the 2‐position of the aromatic ring. They are good synthons in supramolecular chemistry leading to appealing assemblies such as open‐inclusion complexes, capsules and tubes through multiple weak interactions with various guests. Halogen bonding (XB) is a highly directional non‐covalent interaction by an electron‐deficient halogen atom as a donor that interacts with a Lewis base, the XB acceptor. This tutorial review provides an overview of recent advances in halogen‐bonded assemblies based on resorcinarenes and their derivatives, specifically focusing on discrete and capsular assemblies.


Keywords: supramolecular chemistry; chemical bonds

Free keywords: halogen bond; resorcinarenes; cavitands; discrete assemblies; capsules


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Preliminary JUFO rating: 1


Last updated on 2021-23-02 at 14:48