A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
UV laser induced photolysis of glycolic acid isolated in argon matrices (2021)

Krupa, J., Kosendiak, I., Wierzejewska, M., Ahokas, J., & Lundell, J. (2021). UV laser induced photolysis of glycolic acid isolated in argon matrices. Journal of Photochemistry and Photobiology A: Chemistry, 412, Article 113236. https://doi.org/10.1016/j.jphotochem.2021.113236

JYU-tekijät tai -toimittajat

Ahokas, Jussi
Lundell, Jan

Julkaisun tiedot

Julkaisun kaikki tekijät tai toimittajat: Krupa, Justy; Kosendiak, Iwona; Wierzejewska, Maria; Ahokas, Jussi; Lundell, Jan

Lehti tai sarja: Journal of Photochemistry and Photobiology A: Chemistry

ISSN: 1010-6030

eISSN: 1873-2666

Julkaisuvuosi: 2021

Volyymi: 412

Artikkelinumero: 113236

Kustantaja: Elsevier

Julkaisumaa: Sveitsi

Julkaisun kieli: englanti

DOI: https://doi.org/10.1016/j.jphotochem.2021.113236

Julkaisun avoin saatavuus: Ei avoin

Julkaisukanavan avoin saatavuus: 

Julkaisu on rinnakkaistallennettu (JYX): https://jyx.jyu.fi/handle/123456789/74528

Tiivistelmä

The photochemistry of matrix-isolated glycolic acid, induced by UV light, was studied by FTIR spectroscopy and B3LYPD3/6-311++G(3df,3pd) calculations. Several decomposition pathways were found to take place upon 212 nm and 226 nm wavelengths irradiation. A number of complexes formed between photoproducts were identified, among them those of formaldehyde with water, carbon monoxide and carbon dioxide as well as the H2O-CO complexes. The structure and spectroscopic assignment of the photoproducts were made comparing the experimental results with the theoretical predictions and available literature data. The observed formation of different complexes indicates various pathways for their formation resulting from UV-induced photodecomposition of different precursor isomers.

YSO-asiasanat: molekyylit; valokemia; laskennallinen kemia; spektroskopia

Vapaat asiasanat: molecular complexes; vibrational spectroscopy; Matrix isolation; carboxylic acid; computational chemistry

Liittyvät organisaatiot

Hankkeet, joissa julkaisu on tehty

OKM-raportointi: Kyllä

Raportointivuosi: 2021

JUFO-taso: 1